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CC BY 4.0 · Synlett
DOI: 10.1055/a-2560-0282
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A Practical Synthesis of Multi-Site Functionalized Norbornadiene for Molecular Solar Thermal Energy Storage

Monika Shamsabadi
1   Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Gothenburg, Sweden (Ringgold ID: RIN11248)
,
Joost Kimpel
1   Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Gothenburg, Sweden (Ringgold ID: RIN11248)
,
Christian Müller
1   Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Gothenburg, Sweden (Ringgold ID: RIN11248)
,
Kasper Moth-Poulsen 
1   Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Gothenburg, Sweden (Ringgold ID: RIN11248)
2   Catalan Institution for Research & Advanced Studies, Barcelona, Spain
› InstitutsangabenGefördert durch: Göran Gustafssons Stiftelse för Naturvetenskaplig och Medicinsk Forskning
Gefördert durch: Vetenskapsrådet
Gefördert durch: H2020 European Research Council PHOTHERM
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Norbornadienes (NBDs) are promising candidates for molecular solar thermal energy storage (MOST) due to their reversible photoisomerization. A central aspect for future application is the scalable synthesis of NBD derivatives with high solubility. Herein, we report an efficient synthesis and purification of multi-substituted NBDs, achieving diverse substitution patterns and appreciable solubility. The streamlined process for synthesizing and purifying NBDs delivers high yields and purity, which addresses previously significant challenges in NBD-based energy systems. Our findings advance sustainable approaches for MOST through improved NBD stability and usability.



Publikationsverlauf

Eingereicht: 14. Januar 2025

Angenommen nach Revision: 24. Februar 2025

Accepted Manuscript online:
17. März 2025

© . The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting unrestricted use, distribution, and reproduction so long as the original work is properly cited. (https://creativecommons.org/licenses/by/4.0/).

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