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Synthesis 2024; 56(07): 1175-1182
DOI: 10.1055/a-2218-7604
DOI: 10.1055/a-2218-7604
paper
Emerging Trends in Glycoscience
Efficient Preparation of O-Isopropylidene Derivatives of Carbohydrates Catalyzed by Sulfonated Graphene (GR-SO3H) as a Sustainable Acid Catalyst
Abstract
Sulfonated graphene (GR-SO3H) has emerged as a mild, efficient and sustainable catalyst for the preparation of O-isopropylidene derivatives of unprotected and anomeric-protected carbohydrates with acetone and 2,2-dimethoxypropane at room temperature. This methodology not only provides excellent yields but also reduces reaction times, and it demonstrates exceptional recyclability, allowing the catalyst to be reused multiple times.
Key words
acetone - carbohydrates - 2,2-dimethoxypropane - GR-SO3H - O-isopropylidene acetals - sustainabilitySupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2218-7604.
- Supporting Information
Publikationsverlauf
Eingereicht: 04. Oktober 2023
Angenommen nach Revision: 28. November 2023
Accepted Manuscript online:
28. November 2023
Artikel online veröffentlicht:
18. Dezember 2023
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