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CC BY-NC-ND 4.0 · Synlett 2023; 34(14): 1678-1684
DOI: 10.1055/a-2108-8581
DOI: 10.1055/a-2108-8581
synpacts
Published as part of the Special Section 13th EuCheMS Organic Division Young Investigator Workshop
Catalytic Dehydrative Transformations Mediated by Moisture-Tolerant Zirconocene Triflate
Financial support from Lantmännens forskningsstiftelse, Formas (grant no. 2021-00678), the Swedish Foundation for Strategic Research (grant no. FFL21-0005), Stiftelsen Olle Engkvist Byggmästare, Frans Georg och Gull Liljenroths stiftelse, Magnus Bergvalls stiftelse, Stiftelsen Lars Hiertas Minne, and KTH Royal Institute of Technology are gratefully acknowledged.
Abstract
Zirconocene triflate is a powerful moisture-tolerant catalyst for activation of C–O bonds in carboxylic acids and alcohols in the absence of water scavenging techniques. Herein, an overview of the use of this robust metal complex for direct amidation, esterification, and etherification is presented, along with a discussion on mechanistic aspects of the transformations and the catalyst class.
Key words
Lewis acids - homogeneous catalysis - water-tolerant - kinetic analysis - zirconium - amides - esters - ethersPublication History
Received: 08 March 2023
Accepted after revision: 07 June 2023
Accepted Manuscript online:
12 June 2023
Article published online:
11 July 2023
© 2023. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial-License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)
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