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Synthesis 2022; 54(18): 4104-4110
DOI: 10.1055/a-1817-2079
DOI: 10.1055/a-1817-2079
paper
Copper-Catalyzed C–S Formation for the Synthesis of Benzyl Phenyl Sulfides from Dithiocarbamates
The financial support from the Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University (2020ZD02), Hubei Key Laboratory of Biologic Resources Protection and Utilization, Hubei Minzu University (PT012101), State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences (KF2021-06), and the Innovation Fund of Key Laboratory of Green Chemical Process, Ministry of Education, Wuhan Institute of Technology (GCX202102) is greatly appreciated.
Dedicated to the 50th anniversary celebration of Wuhan Institute of Technology
Abstract
An odorless and efficient protocol for the synthesis of benzyl phenyl sulfides is reported. Starting from environmentally friendly phenyl dithiocarbamates and commercially available benzyl halides as starting materials, the target compounds (benzyl phenyl sulfides) could be obtained smoothly and easily by using copper salt as catalyst and Cs2CO3 as base. This method features ligand/additive-free, the use of readily available starting materials, inexpensive catalysts, and good substrate suitability, illustrating its potentially synthetic value for the convenient preparation of some biologically active molecules.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1817-2079.
- Supporting Information
Publication History
Received: 13 March 2022
Accepted after revision: 03 April 2022
Accepted Manuscript online:
05 April 2022
Article published online:
19 May 2022
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