Room Temperature, Metal-Free, Regioselective Arylselenation of Anilines Using Diselenides as Selenium Source

Rekha Bai; Kamlesh Kumar Dabaria; Satpal Singh Badsara

doi:10.1055/a-1730-8186

Synthesis, Table of Contents

Synthesis 2022; 54(10): 2487-2493
DOI: 10.1055/a-1730-8186

paper

Room Temperature, Metal-Free, Regioselective Arylselenation of Anilines Using Diselenides as Selenium Source

Rekha Bai‡

,

Kamlesh Kumar Dabaria‡

,

Satpal Singh Badsara ∗

Abstract

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This work is dedicated to Professor Deevi Basavaiah (University of Hyderabad) on his 71st birthday.

Abstract

A metal-free direct C–H selenation of aniline derivatives via an iodine-catalyzed C–Se bond formation using diselenides as a selenium source at ambient temperature is described. A variety of aniline derivatives underwent regioselective C–H selenation with different diselenides to afford the corresponding aryl selenoethers in good to excellent yields.

Key words

C–H selenation - aniline derivatives - aryl selenoethers - regioselective - metal-free

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References

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