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Synlett 2022; 33(04): 301-306
DOI: 10.1055/a-1695-4979
DOI: 10.1055/a-1695-4979
synpacts
Nickel-Catalyzed Asymmetric Synthesis of P-Stereogenic Vinyl Phosphines
We thank the financial support provided by the Ministry of Science and Technology of the People's Republic of China, National Key R&D Program of China (2018YFA0702001), the National Natural Science Foundation of China (NSFC; 21901235 and 22071224), the University of Science and Technology of China (USTC; KY2060000121, WK2060190095, and KY2060000143), the University of Science and Technology of China (USTC) Research Funds of the Double First-Class Initiative (YD2060002010), and the Anhui Provincial Natural Science Foundation (1908085MB34).
Abstract
Addition reaction to alkynes is an efficient strategy for constructing valuable alkenyl compounds. However, the elusive regioselectivity has been a persistent challenge. In the context of hydrophosphination reaction which could afford valuable P-stereogenic phosphines, the control of enantioselectivity as well as regioselectivity were especially tricky. Here, we highlighted our recent work on the nickel-catalyzed regio- and enantioselective hydrophosphination of unactivated alkynes with in situ generated secondary phosphines.
1 Introduction
2 Hydrophosphination of Alkynes
3 Derivatization Reactions
4 Mechanism Research
5 Summary and Outlook
Key words
P-stereogenic - phosphine compounds - nickel catalysis - hydrophosphination - transition metalsPublication History
Received: 02 November 2021
Accepted after revision: 12 November 2021
Accepted Manuscript online:
12 November 2021
Article published online:
03 December 2021
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