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DOI: 10.1055/a-1581-0235
A Facile Approach to the Synthesis of 3-Acylisoxazole Derivatives with Reusable Solid Acid Catalysts
Autoren
This work was supported by JSPS KAKENHI [Grant-in-Aid for Scientific Research (C) 19K05570].
Abstract
Nitrile oxides were formed from α-nitro ketones using silica gel-supported sodium hydrogen sulfate (NaHSO4/SiO2) or Amberlyst 15 as solid acid catalyst, and then the corresponding 3-acylisoxaszoles were obtained by reacting with alkynes via the 1,3-dipolar [3+2] cycloaddition. These heterogeneous catalysts are easily separable from the reaction mixture and reused. This synthetic method provides a facile, efficient, and reusable production of 3-acylisoxazoles.
Key words
isoxazoles - nitrile oxide - solid acid - supported reagents - acidic polymer - facile synthesisSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1581-0235.
- Supporting Information (PDF) (opens in new window)
Primary Data
- Primary Data (OTHER) (opens in new window)
Primary data for this article are available online at https://zenodo.org/record/5115431#.YTWU1RlxeUl and can be cited using the following DOI: 10.5281/zenodo.5115431.
Publikationsverlauf
Eingereicht: 31. Mai 2021
Angenommen nach Revision: 29. Juli 2021
Accepted Manuscript online:
09. August 2021
Artikel online veröffentlicht:
08. September 2021
© 2021. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial-License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/)
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