Nickel-Catalyzed Hydrodeoxygenation of Aryl Sulfamates with Alcohols as Mild Reducing Agents

Kasumi Matsuo; Masami Kuriyama; Kosuke Yamamoto; Yosuke Demizu; Koyo Nishida; Osamu Onomura

doi:10.1055/a-1548-8362

Synthesis, Table of Contents

Synthesis 2021; 53(23): 4449-4460
DOI: 10.1055/a-1548-8362

paper

Nickel-Catalyzed Hydrodeoxygenation of Aryl Sulfamates with Alcohols as Mild Reducing Agents

Kasumi Matsuo

^aGraduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan

,

Masami Kuriyama ∗

^aGraduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan

,

Kosuke Yamamoto

^aGraduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan

,

Yosuke Demizu

^bDivision of Organic Chemistry, National Institute of Health Sciences, 3-25-26 Tonomachi, Kawasaki, Kanagawa 210-9501, Japan

,

Koyo Nishida

^aGraduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan

,

Osamu Onomura ∗

^aGraduate School of Biomedical Sciences, Nagasaki University, 1-14 Bunkyo-machi, Nagasaki 852-8521, Japan

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Abstract

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Abstract

The nickel-catalyzed hydrodeoxygenation of aryl sulfamates has been developed with alcohols as mild reductants. A variety of functional groups and heterocycles were tolerated in this reaction system to give the desired products in high yields. In addition, the gram-scale process and stepwise cine-substitution were also achieved with high efficiency.

Key words

nickel - reduction - hydrodeoxygenation - sulfamate - alcohol

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References

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