Nickel-Catalyzed Hydrodeoxygenation of Aryl Sulfamates with Alcohols as Mild Reducing Agents

Abstract

The nickel-catalyzed hydrodeoxygenation of aryl sulfamates has been developed with alcohols as mild reductants. A variety of functional groups and heterocycles were tolerated in this reaction system to give the desired products in high yields. In addition, the gram-scale process and stepwise cine-substitution were also achieved with high efficiency.

Key words

nickel - reduction - hydrodeoxygenation - sulfamate - alcohol

Publication History

Received: 14 June 2021

Accepted after revision: 13 July 2021

Accepted Manuscript online:
13 July 2021

Article published online:
17 August 2021

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