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Synthesis 2021; 53(21): 4086-4096
DOI: 10.1055/a-1541-6271
DOI: 10.1055/a-1541-6271
paper
Direct and Efficient Synthesis of Sulfonium Acyl Sulfonylmethylide Ylides from Acetylenic Sulfones and Dimethyl Sulfoxide
This work was supported partially from the National Natural Science Foundation of China (nos. 21772010 and 21572017) and the Fundamental Research Funds for the Central Universities (XK1802-6).
Abstract
Bifunctionalized sulfonium ylides – sulfonium acyl sulfonylmethylides – were directly and efficiently prepared from various acetylenic sulfones and aliphatic sulfoxides under heating conditions. The current method features short reaction time, low cost, readily available starting materials, convenient operation, and purification, providing an efficient access to widely applied bifunctionalized sulfonium ylides.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1541-6271.
- Supporting Information
Publication History
Received: 24 May 2021
Accepted after revision: 30 June 2021
Accepted Manuscript online:
30 June 2021
Article published online:
29 July 2021
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