Recent Advances and the Prospect of Hypervalent Iodine Chemistry

Xiao-Guang Yang; Ze-Nan Hu; Meng-Cheng Jia; Feng-Huan Du; Chi Zhang

doi:10.1055/a-1492-4943

Synlett, Inhaltsverzeichnis

Synlett 2021; 32(13): 1289-1296
DOI: 10.1055/a-1492-4943

cluster account

Perspectives on Organoheteroatom and Organometallic Chemistry

Recent Advances and the Prospect of Hypervalent Iodine Chemistry

Xiao-Guang Yang

,

Ze-Nan Hu

,

Meng-Cheng Jia

,

Feng-Huan Du

,

Chi Zhang∗

Abstract

Alle Artikel dieser Rubrik

Dedicated to the College of Chemistry, Nankai University, on its 100^th anniversary

Abstract

Nowadays, hypervalent iodine chemistry has remarkably advanced in parallel with the emergence of novel hypervalent iodine reagents. Hypervalent iodine reagents, due to their outstanding characteristics including rich reactivities, excellent chemoselectivity, stability, and environmental friendliness, are becoming more and more popular in the synthetic organic chemistry. In this Account, a number of recent elegant research works and our perspective on the future of hypervalent iodine chemistry is presented.

1 Introduction

2 Recent Advances and Discussion

2.1 Novel Reactivities of Hypervalent Iodine Reagents

2.2 Atom-Economical Reactions Promoted by Hypervalent Iodine Reagents

2.3 Other Applications of Hypervalent Iodine Reagents

2.4 The Applications of DFT Calculations in Elucidating Reaction Mechanism Involving Hypervalent Iodine Reagents

3 Outlook and Conclusion

Key words

hypervalent iodine - oxidation - functional group transfer - atom economy - DFT calculation

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Referenzen

References and Notes
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