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Synthesis 2021; 53(09): 1654-1662
DOI: 10.1055/a-1336-5720
paper

Oxidative C–H Acyloxylation of Acetone with Carboxylic Acids under Iodine Catalysis

Xiao-Yu Zhou∗
,
Xia Chen
The work was supported by the Foundation of Guizhou Educational Committee (Grant No. qianjiaohe KY zi [2019] 081) and the Natural Science Foundation of Guizhou Province (Grant No. qiankehejichu [2018] number 1141)
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Abstract

Iodine-catalyzed oxidative C(sp3)–H acyloxylation of acetone with carboxylic acids has been developed. The method employs iodide­ as catalyst and sodium chlorite as oxidant. Substituted benzoic acids, naphthoic acids and heteroaromatic carboxylic acids can be used, and 2-oxopropyl carboxylates are obtained with good to excellent yields.

Key words

iodine - oxidative C–H functionalization - acetone - carboxylic acids - carboxylates

Supporting Information

    Supporting information for this article is available online at https://doi.org/10.1055/a-1336-5720.
  • Supporting Information


Publication History

Received: 04 November 2020

Accepted after revision: 14 December 2020

Accepted Manuscript online:
14 December 2020

Article published online:
12 January 2021

© 2020. Thieme. All rights reserved

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