Sulfonated Tetraphenylethylene-Based Hypercrosslinked Polymer as a Heterogeneous Catalyst for the Synthesis of Symmetrical Triarylmethanes via a Dual C–C Bond-Cleaving Path

Abstract

A sulfonic acid functionalized tetraphenylethylene-based hypercrosslinked polymer (THP-SO₃H) with a well-developed porous network and accessible sulfonic acid sites was synthesized and characterized by different analytical techniques. The catalytic prowess of the synthesized material THP-SO₃H was investigated in a challenging dual C–C bond-breaking reaction for the synthesis of symmetrical triarylmethanes (TRAMs) in high yield. The scope of the developed metal-free method was also explored with a wide variety of substrates. The organocatalyst can be easily recovered by filtration and reused up to five consecutive cycles without substantial loss in its catalytic efficacy.

Key words

hypercrosslinked polymer - heterogeneous catalyst - reusable - C–C bond breaking - triarylmethane

Publication History

Received: 12 July 2020

Accepted after revision: 01 October 2020

Accepted Manuscript online:
01 October 2020

Article published online:
27 November 2020

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