Asymmetric Aza-Diels-Alder Reaction Catalyzed by Boron Reagent: Effect of  Biphenol and Binaphthol Ligand

Kouji Hattori; Hisashi Yamamoto

doi:10.1055/s-1993-22374

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Synlett 1993; 1993(2): 129-130
DOI: 10.1055/s-1993-22374

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Asymmetric Aza-Diels-Alder Reaction Catalyzed by Boron Reagent: Effect of Biphenol and Binaphthol Ligand

Kouji Hattori^* , Hisashi Yamamoto

^*Department of Applied Chemistry, Nagoya University, Chikusa, Nagoya 464-01, Japan

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Publication Date:
19 March 2002 (online)

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An asymmetric aza-Diels-Alder reaction of chiral imine catalyzed by an in situ generated achiral and chiral boron complex is described. The method is successful with both aromatic and aliphatic aldimines and affords products of up to 99% de.