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Synthesis 1992; 1992(11): 1078-1080
DOI: 10.1055/s-1992-26306
short paper
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Glycosylation of Mycotoxins

Susanne Grabley* , Manfred Gareis, Winfried Böckers, Joachim Thiem
  • *Hoechst AG, Hauptlaboratorium G 830, Postfach 80 03 20, D-6230 Frankfurt 80, Germany
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Publikationsdatum:
17. September 2002 (online)

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Glycoconjugates of some mycotoxins were prepared by the phasetransfer catalyzed glucosylation procedure. With zearalenone a regio- and stereospecific glucosylation gave the natural derivative which proved to be a "masked mycotoxin". In the case of ochratoxin A glucosylation occurred exclusively at the amino acid part to give an unusual sugar ester component.