PDF herunterladen
Synlett 1992; 1992(4): 293-294
DOI: 10.1055/s-1992-21343
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Samarium-Catalyzed Electrochemical Cyanomethylation of Esters

Hassan Hébri* , Elisabet Duñach, Jacques Périchon
  • *Laboratoire d'Electrochimie, Catalyse et Synthèse Oranique, C.N.R.S., UMR no 28, 2 rue Henri-Dunant, F-94320 Thiais, France
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
08. März 2002 (online)

 als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

A series of ß-oxonitriles 1 were obtained in good yields through the electrochemical coupling of nitriles with aromatic or aliphatic esters. The reaction was catalyzed by samarium(III) chloride using tert-butyl alcohol as a probase. Electrolyses were run under mild conditions in an undivided cell with a magnesium anode.