Dicyclopentadienyltitanium Halide Induced Reduction of Nitroarenes and Organic Halides

Yanlong Qian; Guisheng Li; Xiaofan Zheng; Yao-Zeng Huang

doi:10.1055/s-1991-20772

RSS-Feed abonnieren

Bitte kopieren Sie die angezeigte URL und fügen sie dann in Ihren RSS-Reader ein.

https://www.thieme-connect.de/rss/thieme/de/10.1055-s-00000083.xml

Teilen / Bookmarken

Facebook Linkedin Weibo

PDF herunterladen

Synlett 1991; 1991(7): 489-490
DOI: 10.1055/s-1991-20772

letter

© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Dicyclopentadienyltitanium Halide Induced Reduction of Nitroarenes and Organic Halides

Yanlong Qian^* , Guisheng Li, Xiaofan Zheng, Yao-Zeng Huang

^*Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shanghai 200032, People's Republic of China

Weitere Informationen

Publikationsverlauf

Publikationsdatum:
07. März 2002 (online)

als PDF herunterladen Lizenzen und Reprints Alle Artikel dieser Rubrik

Nitroarenes are reduced by dicyclopentadienyltitanium chloride (Cp₂TiCl) to azo compounds in moderate yield while benzylic and allylic chlorides and vicinal dibromides are catalytically transformed to the corresponding coupling products and alkenes, respectively, by the dicyclopentadienyltitanium dichloride/aluminum system.