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Synthesis 1989; 1989(4): 291-292
DOI: 10.1055/s-1989-27227
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Studies on Enantioselective Addition of Chiral Titanium Reagents to Aromatic Aldehydes

Ji-Tao Wang* , Xiuju Fan, Xiao Feng, Yi-Min Qian
  • *Department of Chemistry, Nankai University, Tianjin, People's Republic of China
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Publication Date:
17 September 2002 (online)

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A series of substituted chiral benzhydrols were synthesized by reaction of aromatic aldehydes with the chiral intermediates formed from chiral titanates and arylmagnesium halides. The effect of substituents on the enantioselectivity of the reaction is studied. The reactions are carried out with two different chiral intermediates using two different procedures.