Direct Trifluoromethylthiolation Reactions Involving Radical Processes

Anne-Laure Barthelemy; Emmanuel Magnier; Guillaume Dagousset

doi:10.1055/s-0037-1611278

Synthesis, Table of Contents

Synthesis 2018; 50(24): 4765-4776
DOI: 10.1055/s-0037-1611278

short review

Direct Trifluoromethylthiolation Reactions Involving Radical Processes

Authors

Anne-Laure Barthelemy
Emmanuel Magnier
Guillaume Dagousset *

Institut Lavoisier de Versailles, UMR 8180, Université de Versailles-Saint-Quentin, 78035 Versailles Cedex, France Email: guillaume.dagousset@uvsq.fr

Abstract

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Abstract

An overview of the most significant radical-based synthetic methods currently available for the preparation of trifluoromethylthiolated compounds is presented.

1 Introduction

2 Early Work: Photochemical Reactions Under UV Irradiation

2.1 Reactions Involving CF₃SH

2.2 Reactions Involving CF₃SCl

2.3 Reactions Involving CF₃SSCF₃

3 Reactions Involving a Nucleophilic SCF₃ Reagent

3.1 Reactions with CuSCF₃

3.2 Reactions with AgSCF₃

4 Reactions Involving an Electrophilic SCF₃ Reagent

4.1 Reactions Involving the Formation of an R^• Radical

4.2 Reactions involving the formation of ^•SCF₃ Radical

5 Conclusion

Key words

trifluoromethythiolation - radicals - silver-mediated oxidative transformations - photoredox catalysis - electrophilic SCF₃ reagents

Full Text

References

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