A General and Efficient Synthesis of Nitrogen-Substituted Ferrocenes

Salih Özçubukçu; Ellen Schmitt; Annika Leifert; Carsten Bolm

doi:10.1055/s-2006-958961

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Synthesis 2007(3): 389-392
DOI: 10.1055/s-2006-958961

PAPER

A General and Efficient Synthesis of Nitrogen-Substituted Ferrocenes

Salih Özçubukçu, Ellen Schmitt, Annika Leifert, Carsten Bolm*
Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
Fax: +49(241)8092391; e-Mail: Carsten.Bolm@oc.RWTH-Aachen.de;

Further Information

Publication History

Received 6 October 2006
Publication Date:
21 December 2006 (online)

Abstract
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Abstract

Copper(I) iodide mediated Ullmann-type coupling reactions of iodoferrocene and 1,1′-diiodoferrocene has been used to synthesize N-substituted ferrocenes that are difficult to obtain by classical methods. In this manner, a range of Fc-[N]-R-type compounds have been prepared in moderate to good yields.

Key words

copper - cross-coupling - ferrocene - heterocycle - Ullmann coupling

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