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Synthesis 1999; 1999(4): 676-682
DOI: 10.1055/s-1999-3438
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Chemoselective Syntheses of Various Cyanofluoromethylene Compounds from Organic Bromides by Use of Sodium Triethylgermanate(IV) and Its Mechanistic Studies

Yasuo Yokoyama* , Kunio Mochida
  • *Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Toshima-ku, Tokyo 171-8588, Japan; Fax +81(3)59 92 10 29; E-mail: 940429@gakushuin.ac.jp
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Publication Date:
31 December 1999 (online)

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The chemoselective syntheses of various cyanofluoromethylene compounds proceeded through the formation of the cyanofluoromethyl anion from 2-fluoro-2-phenyl-2-phenyl-thioacetonitrile by the use of sodium triethylgermanate(IV) (Et3GeNa).

germanium reagents - fluorine derivatives - carbonitriles - mechanism

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