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Synthesis 1995; 1995(9): 1071-1073
DOI: 10.1055/s-1995-4055
short paper
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Trichloronitromethane with Acyl Chlorides in the Presence of Tin(II) Chloride: Synthesis of Trichloronitro Ketones

Ayhan S. Demir* , Cihangir Tanyeli, Hilal Aksoy, Volkan Gulbeyaz, Ali S. Mahasneh
  • *Department of Chemistry, Middle East Technical University, 06531 Ankara, Turkey, Fax +90(312)2101280; E-mail asdemir@rorqual.cc.metu.edu.tr
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Publication History

Publication Date:
31 December 2000 (online)

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Trichloronitromethane adds to acid chlorides in the presence of tin(II) chloride to yield dichloronitro ketones via a substitution reaction. Reduction and dechlorination of the dichloronitro ketones give dichloroamino alcohols and nitro ketones, respectively, in good yield.

The reaction of trichloronitromethane with acid chlorides gives the dichloronitro ketones

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