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Synthesis 1993; 1993(8): 819-823
DOI: 10.1055/s-1993-25949
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A Synthesis of Allylic Diphenylphosphinic Esters

J. Stuart Mccallum* , Lanny S. Liebeskind
  • *Department of Chemistry, Emory University, Atlanta, Georgia 30322, USA
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Publication History

Publication Date:
27 September 2002 (online)

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The preparation of diphenylphosphinate esters of allylic alcohols is reported. Addition of allylic alcohols to the imidazolinium salt prepared in situ from diphenylphosphinic chloride and imidazole or to 1-(diphenylphosphinoyl)imidazole produces the corresponding diphenylphosphinate esters in good to excellent yields.

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