Synthesis 1992; 1992(12): 1273-1276
DOI: 10.1055/s-1992-26356
paper
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A New Route to 3H-1,5-Benzodiazepines and Heterocylic Ketene Aminals from Benzoyl Substituted Ketene Dithioacetals and Diamines

Zhi-Tang Huang* , Mei-Xiang Wang
  • *Institute of Chemistry, Academia Sinica, Beijing, 100080, People's Republic of China
Further Information

Publication History

Publication Date:
29 April 2002 (online)

Heterocyclic ketene aminals 5 or 3H-1,5-benzodiazepines 4 were obtained from the reaction of benzoyl substituted ketene dithioacetals 1 with various diamines 2. The mechansim of formation of these two different products are discussed.

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