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Synthesis 1991; 1991(11): 967-969
DOI: 10.1055/s-1991-26619
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Arylation of Camphene with Arenediazonium Salts Catalyzed by Palladium Acetate

Wang Yong* , Pang Yi, Zhang Zhuangyu, Hu Hongwen
  • *Department of Chemistry, Nanjing University, Nanjing, People's Republic of China
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Publication Date:
29 April 2002 (online)

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(E)-8-Arylcamphenes 3 were obtained in moderate to good yields by the reaction of camphene (1) with a variety of arenediazonium tetrafluoroborates 2 in the presence of palladium acetate under mild conditions. The E-configuration of the products was confirmed by 1H-NMR analyses of the reaction mixtures of photoisomerization of 3, the Nuclear Overhauser Effect (NOE) of 3a and by comparison with an authentic sample of 4j.

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