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Synthesis 1991; 1991(3): 204-206
DOI: 10.1055/s-1991-26419
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Preparation of Phenylalkyl Ethers and Phenyl Esters from Benzenediazonium Tetrafluoroborate with Alkoxytrimethylsilanes and Trimethylsilyl Esters

George A. Olah* , An-hsiang Wu
  • *Donald P. and Katherine B. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA 90089-1661, USA.
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Publication Date:
17 September 2002 (online)

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Sonication assisted reaction of benzenediazonium tetrafluoroborate with alkoxytrimethylsilanes and trimethylsilyl esters gives phenylalkyl ethers and phenyl esters, respectively, with trialkyl-(aryl) borates as byproducts. The scope of the reaction, experimental conditions and proposed mechanism are discussed.

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