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Synthesis 1990; 1990(9): 850-852
DOI: 10.1055/s-1990-34093
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Vicarious Nucleophilic Substitution of Hydrogen in Nitroarenes by Carbanions of Alkyl Dichloroacetates. Some New Transformations of Chloro(nitroaryl)acetates

Mieczysław Makosza* , Krzysztof Sienkiewicz, Krzysztof Wojciechowski
  • *Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44/52, PL-01-224 Warsaw, Poland
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Publication Date:
17 September 2002 (online)

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Vicarious Nucleophilic Substitution of Hydrogen in nitroarenes by ethyl dichloroacetate anion provides ethyl chloro(nitroaryl)acetates, which can be transformed into ethyl imino(nitroaryl)acetates and ethyl oxo(nitroaryl)acetates by treatment with sodium azide.