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Synthesis 1989; 1989(8): 614-616
DOI: 10.1055/s-1989-27334
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A Simple Method for the Conversion of Adamantyl, Benzyl and Benzyhydryl Alcohols to Their Corresponding Bromides and Chlorides and the Transhalogenation of Adamantyl, Benzyl, Benzhydryl and Tertiary Alkyl Bromides and Chlorides

A. Amrollah-Madjdabadi* , Tung N. Pham, E. C. Ashby
  • *School of Chemistry, Georgia Institute of Technologie, Atlanta, GA 30332, USA
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Publication Date:
17 September 2002 (online)

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Adamantyl, benzyl, and benzhydryl alcohols have been converted to their corresponding bromides and chlorides in the absence of a solvent, rapidly and in high yield using boron tribromide and tin(IV) chloride, respectively. Additionally the above bromides and chlorides can be interconverted by a transhalogenation process using the same reagents in the absence of solvent.