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Synthesis 1988; 1988(11): 907-910
DOI: 10.1055/s-1988-27750
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Thermal Oxidative Deamination of Aliphatic Amines to Aldehydes with Bis(diphenylphosphinyl) Peroxide

Guy Masse* , Georges Sturtz
  • *Laboratoire de Chimie Hétéroorganique, Faculté des Sciences et Techniques, Avenue Victor Le Gorgeu, F-29287 Brest Cedex, France
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Publication Date:
20 August 2002 (online)

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Reaction of N-substituted alkylamines having pseudoacidic hydrogen at the 1-methylene group with bis(diphenylphosphinyl) peroxide yields the deaminated products by thermal elimination of diphenylphosphinic acid from the intermediate O-diphenylphosphinylhydroxylamines.

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