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Synthesis 1987; 1987(8): 716-718
DOI: 10.1055/s-1987-28057
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Preparation of Dimethyl (1-Formylalkyl)phosphonates via Singlet Oxygen Adducts

Mitsuji Yamashita* , Hiroyuki Nomoto, Hiroyuki Lmoto
  • *Department of Applied Chemistry, Faculty of Engineering, Shizuoka University, Hamamatsu 432, Japan
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Publication Date:
12 September 2002 (online)

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The nitro group of dimethyl (1-nitromethylalkyl)phosphonates is conveniently converted into a formyl group by reaction with singlet oxygen to give dimethyl (1-formylalkyl)phosphonates. (1-Formylbutyl)diphenylphosphine oxide is prepared by the same reaction.

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