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Synthesis 1987; 1987(1): 65-66
DOI: 10.1055/s-1987-27848
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A Facile Synthesis of Pentafluorophenyl Olefins via an Arsonium Ylide

Yanchang Shen* , Weiming Qiu
  • *Shanghai Institute of Organic Chemistry, Academia Sinica, 345 Lingling Lu, Shanghai, People's Republic of China
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Publication Date:
20 August 2002 (online)

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The in situ reaction of (pentafluorophenylmethylene)triphenylarsorane, generated from methylenetriphenylarsorane and hexafluorobenzene, with aromatic aldehydes gives good to excellent yields of pentafluorophenyl olefins with high stereoselectivity.

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