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Synthesis 1986; 1986(5): 386-388
DOI: 10.1055/s-1986-31645
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(η6-Arene)-tricarbonylchromium Complexes in Organic Synthesis: Stereoselective Carbon-Carbon Bond Formation via (η6-Arene)- tricarbonylchromium Carbocations

Motokazu Uemura* , Toshio Kobayashi, Yuji Hayashi
  • *Faculty of Science, Osaka City University, Sugimoto 3-3-138, Sumiyoshi-ku, Osaka 558, Japan
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Publikationsdatum:
27. September 2002 (online)

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The benzylic acetate or hydroxy group of (η6-arene)-tricarbonylchromium complexes gave exo-substituted chromium complexes via Cr(CO)3-stabilized carbocations by the reaction with allyltrimethylsilane or propargyltrimethylsilane in the presence of Lewis acid.

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