PDF herunterladen
Synthesis 1985; 1985(9): 871-873
DOI: 10.1055/s-1985-31366
communication
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

2-Cyclopropen-1,1-dicarbonsäure- und Bicyclo[1.1.0]butan-2,2-dicarbonsäure-diester

Günther Maier* , Bernd Wolf
  • *Institut für Organische Chemie der Universität Gießen, Heinrich-Buff-Ring 58, D-6300 Gießen, Bundesrepublik Deutschland
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
27. September 2002 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

2-Cyclopropene-1,1-dicarboxylic and Bicyclo[1.1.0]butane-2,2-dicarboxylic Diesters Cyclopropenation of bis[trimethylsilyl]-acetylene with diazomalonic esters affords 2,3-disilylated cyclopropene-1,1-dicarboxylic esters which are desilylated to 2-cyclopropene-1,1-dicarboxylic esters by treatment with potassium fluoride/crown ethers in acetonitrile. Two independent routes to silylated and non-silylated bicyclobutane-2,2-dicarboxylic esters are described.

      >