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Synthesis 1985; 1985(9): 846-849
DOI: 10.1055/s-1985-31362
DOI: 10.1055/s-1985-31362
paper
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γ-Substituted Secondary Organoalkaline Compounds and their Chlorinated Precursors: Synthetic Applications
Further Information
Publication History
Publication Date:
27 September 2002 (online)
The prepartion of γ-functionalised secondary organolkaline metal compounds starting from methyl 3-chlorobutanoate (obtained by addition of hydrogen chloride to commercially available methyl trans-2-butenoate) is described. Reactions of these metallated compounds with suitable electrophilic reagents leads to a variety of tertiary alcohol derivatives.