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Synthesis 2020; 52(02): 297-303
DOI: 10.1055/s-0039-1690031
DOI: 10.1055/s-0039-1690031
paper
DMSO-Mediated Synthesis of Methylene-Bridged Unsymmetrical Bisamides in the Presence of AcOH
This work was supported by the financial support from Natural Science Foundation of Zhejiang Province (LY19H300001) is gratefully acknowledged.Weitere Informationen
Publikationsverlauf
Received: 30. Juli 2019
Accepted after revision: 22. September 2019
Publikationsdatum:
09. Oktober 2019 (online)
§ These authors contributed equally.
Abstract
A simple and efficient procedure for the synthesis of N-[(methylthio)methyl]benzamides and methylene-bridged unsymmetrical bisamides was achieved mediated by DMSO in the presence of acetic acid. DMSO plays a dual role in the transformation, as not only a solvent, but also an environmentally benign methylene source. The protocol provides new strategies for effective synthesis of unsymmetrical bisamides and avoids the use of transition-metal catalysts.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690031.
- Supporting Information
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