DOI: 10.1055/s-00000131

Synfacts

Ausgabe 12 · Volume 20 · Dezember 2024 DOI: 10.1055/s-014-60584

Synform

  • A183

    SYNFORM ISSUE 2024/12

    • Synthesis of Natural Products

  • z1233

    All PDFs of this category

  • 1233

    Total Synthesis of (±)-Niduterpenoid B

  • 1234

    Total Synthesis of (±)-Erythrinine and Congeners

  • 1235

    Total Synthesis of (+)-Formicamycin H

  • 1236

    Chemoenzymatic Synthesis of (+)-Tetrandrine

  • 1237

    Total Synthesis of (–)-Flueggeacosine C

  • 1238

    Total Synthesis of (–)-Dithiosilvatin and (–)-Bilain A

  • 1239

    Total Synthesis of (–)-Tetracycline

    • Synthesis of Heterocycles

  • z1241

    All PDFs of this category

  • 1241

    Biocatalytic, Enantioselective Synthesis of Lactams

  • 1242

    Synthesis of Difluoromethylpyrazoles from Difluoroacetohydrazonoyl Bromides and Nitriles

  • 1243

    Synthesis of Spiroketals via a Copper-Catalyzed [3+2] Annulation of Sulfonyl Enamides

  • 1244

    Simple, Regioselective Multicomponent Reaction to Achieve Pentacyclic Systems Based on Quinolines

  • 1245

    Substituted Imidazoles via Cobalt-Catalyzed Coupling of Enaminones with Oxadiazolones

  • 1246

    Tertiary Nitroalkanes through the Hydronitration of Olefins

  • 1247

    Stereocontrolled Syntheses of Bicyclic Diaza[3.3.0]octane Carboxylic Acids

  • 1248

    Direct Formation of CF2H Derivatives from Alcohols

  • 1249

    Mild SNAr-Approach to 2-Aminopyridines

  • 1250

    Modular Access to Functionalized 1,6-Naphthyridones

  • 1251

    Versatile Difunctionalization of Aryne Derivatives

  • 1252

    General Ether Synthesis through the Cross-Coupling of Alcohols with Olefins

    • Synthesis of Materials and Unnatural Products

  • z1253

    All PDFs of this category

  • 1253

    Nonplanar Nanographene with 85 Fused Rings

  • 1254

    Radical–Radical C–C Coupling-Enabled [4]Rhombenes

  • 1255

    Four-Membered-Ring-Embedded Polycycloarene

  • 1256

    4,5-Fused Open-Shell Bis-Fluorenes

  • 1257

    Chacolgen-Containing Spiro-Buckybowls

  • 1258

    Helicenes with a BN Inner Rim

  • 1259

    Crystalline Triangular Triboron

  • 1260

    A BN-Benzvalene

  • 1261

    Trapping m-Benzyne

  • 1262

    Dicarbofunctionalized Cyclooctene Monomers

  • 1263

    Mechanically Gated Degradation of Polyethylenes

  • 1264

    Potassium-Ion- versus Palladium-Promoted Alkyne Cyclotrimerization

    • Metals in Synthesis

  • z1265

    All PDFs of this category

  • 1265

    Copper-Catalyzed Cross-Nucleophile Alkylarylation of Vinylarenes with Two Different Boronic Acids

  • 1266

    Atroposelective Synthesis of Biheteroaryl Isoquinolines via Palladium Catalysis

  • 1267

    Photoredox-Catalyzed Radical Alkyl Transfer Using Recyclable Sulfoximines

  • 1268

    Synthesis of Biaryls via Nickel-Catalyzed Cross-Coupling

  • 1269

    Solvent-Controlled C(sp2)–H-Fluoroalkylation of (Hetero)Arenes with CF2Br2 under Photocatalysis

  • 1270

    Synthesis of Disubstituted Benzofulvenes via Palladium Catalysis

  • 1271

    Rearrangement of Vinylcyclobutanones to β,γ-Unsaturated Cyclohexanones

  • 1272

    Synthesis of Triarylated Enynes via Palladium Catalysis

  • 1273

    Primary Amination of C(sp3)–H Bonds Enabled by a Protonated Iron–Nitrene Complex

  • 1274

    Nickel-Catalyzed, Highly Selective, and Convergent Allylic Substitution of Allyl Chlorides with Phenols

  • 1275

    Regioselective Radical Hydrohalogenation and Hydroazidation of Alkenes through Iron Catalysis

  • 1276

    4+3 Reaction of 4-Hydroxymethylindoles and Aziridines Providing Azepinoindoles via Copper Catalysis

  • 1277

    Asymmetric Alkylarylation of Olefins with Alkanes and Aryl Halides via a Photoelectrocatalytic Approach

  • 1278

    Synthesis of α-Amino Acids via a Pd(II) C–H Activation/Desymmetrization of Amino Carboxylic Acids

  • 1279

    Copper-Catalyzed Asymmetric Sulfur-Arylation of Sulfenamides via Chan–Lam-Type Coupling

  • 1280

    Asymmetric Heterodimerization of Enamides and Olefins via Nickel Catalysis

  • 1281

    Palladium-Catalyzed Asymmetric β,γ-Dehydrogenation of Cycloalkyl Amides to Access Chiral Carbocycles

  • 1282

    Regiodivergent Asymmetric Synthesis of 1,2- and 1,3-Amino Alcohols from Allylamines

  • 1283

    Nickel-Catalyzed Decarbonylative C(sp3)–C(sp3) Cross-Electrophile Coupling

  • 1284

    Copper-Catalyzed Synthesis of Unsymmetrical Diaryl Sulfides Using an Odorless Sulfur Source

  • 1285

    A Protolysis Approach Enables Samarium-Catalyzed Reductive Cross-Coupling of Ketones and Acrylates

  • 1286

    Metallophotoredox-Enabled Z-Selective Hydroalkylation of Alkynes and Tandem Z–E Inversion

  • 1287

    Selective Hydro- and Carbocyanation of Alkynes via Photoexcited Nickel Catalysis

  • 1288

    Reductive Desymmetrization of Malononitriles Enabled by Cobalt Catalysis

  • 1289

    Asymmetric Cross Coupling of Racemic H-Phosphinamides with Aryl and Vinyl Bromides

  • 1290

    A Carbonylative Narasaka–Heck Cyclization: Aminoacylation of Unsaturated Oxime Esters

    • Polymer-Supported Synthesis

  • z1291

    All PDFs of this category

  • 1291

    Single-Atom Zinc-Catalyzed C/N-Alkylation through Borrowing Hydrogen Processes

  • 1292

    Photocatalytic Oxidative Condensation of Benzyl Alcohols and Anilines with MIL-53(Fe) MOF

  • 1293

    Photocatalytic S–N Coupling of Thiols and Amines by K-Doped Copolymers of Triaminoheteroarenes

  • 1294

    C–H Activation Using a CdS Quantum Dots Gel as a Hydrogen-Atom-Transfer Photocatalyst

  • 1295

    Nano-Cobalt-Catalyzed Reductive Amination of Aldehydes and Ketones with NH3 and H2

  • 1296

    Photocatalytic Oxidative Dimerization of Amines with Borotungstate Polyoxometalates Bearing P, As, or Si

  • 1297

    Enantioselective 1,4-Reduction of Conjugated Aldehydes by Carbon Dots and Chiral Phosphoric Acids

  • 1298

    Polymer-Supported nano Pd-Catalyzed Hydrogenolysis of O- and N-Benzyl Groups in Water with B2(OH)4

  • 1299

    Pd/Cu Supported on Defective MOFs for Oxidative Aminoamidation of N-Sulfonyl-2-Allylanilines

  • 1300

    Acceptorless Dehydrogenative Coupling for the Synthesis of Quinolines Using a Single-Atom Fe Catalyst

  • 1301

    Reductive Amination of Carbonyl Compounds with Amines or Ammonia Using a Single-Atom Iron Catalyst

    • Organo- and Biocatalysis

  • z1303

    All PDFs of this category

  • 1303

    Direct Asymmetric Functionalization of α‑Amino C–H Bonds

  • 1304

    Non-Natural Photodecarboxylase Enables Stereospecific Radical Coupling of Enals and Carboxylic Acids

  • 1305

    Efficient Hydrogen Evolution Reaction Catalyzed by an N-Heterocyclic Phosphine

  • 1306

    Chiral Phosphoric Acid Catalyzed Enamine C-Acylation for the Synthesis of Pyrrolinones and Indolinones

  • 1307

    Access to Enantiopure 2-Azabicyclo[3.1.1]heptane Derivatives via Lewis Acid Catalysis

  • 1308

    Pyridine Synthesis via Unprecedented 6-endo-Cyclization of Cyclopropylamides with Alkynes

  • 1309

    Chiral Lewis Base Catalyst Enables Asymmetric Multicomponent 1,2-Boronate Rearrangement

  • 1310

    Stereoselective Tandem Biocatalytic Reaction to Access Saturated N-Heterocycles

  • 1311

    Aldehyde–Olefin Couplings via Sulfoxylate-Mediated Oxidative Generation of Ketyl Radical Anions

  • 1312

    Enzymatic α-Amination of Alkylcarboxylic Acid Esters

    • Innovative Drug Discovery and Development

  • z1313

    All PDFs of this category

  • 1313

    Cleavable Linker Delivers Increased Solubility of Highly Insoluble Small-Molecule Therapeutics

  • 1314

    Displacement of a Water Molecule Enhances Drug Residence Time

  • 1315

    A Scalable and Sustainable Transition-Metal-Free Stereoretentive Decarboxylative Amidation

  • 1316

    Chiral β-Branched Amines via Enzymatic Asymmetric Reductive Amination

  • 1317

    Pulling the Brake on Neuromuscular Blocking Agents: New Host Molecule as Potential Universal Antagonist

  • 1318

    Oxadiazolines as Tools for Photoaffinity Labeling

  • 1319

    Preparing Trifluoromethyl Analogues with Boronic Acids and Rhodium

  • 1320

    Csp3–H Functionalization of Sugar Derivatives

  • 1321

    Hydroxyaryl-Tetrazines Enable Fast and Efficient Biorthogonal Click-to-Release

  • 1322

    Fragment Coupling Approach Enables Expedient Access to Bioactive Norcembranoid Natural Products

  • 1323

    Immunosuppressive Macrocycles Accessed through a Fragment Coupling Approach

  • 1324

    Identification of New Leads for the Indazole-Based LRRK2 Inhibitors

  • 1325

    Aldol Cyclization with a Twist: Asymmetric Approach Yields CF3-Functionalized Heterospirocycles

  • 1326

    Development of Catalyst Differentiation Strategy to Synthesize Amines

  • 1327

    Synthesis of Multitarget Ligands for Alzheimer’s Disease

    • Peptide Chemistry

  • z1329

    All PDFs of this category

  • 1329

    Peptide Synthesis Using Unprotected Amino Acids

  • 1330

    Late-Stage Functionalization for the Introduction of Sulfilimines into Peptides

  • 1331

    Photoredox Catalysis for Site-Selective Aklylation of Glycine and Glycine-Containing Peptides

  • 1332

    Iridium-Catalyzed Photoredox Functionalization of Glycine Derivatives

  • 1333

    Enantioselective Synthesis of Unnatural α-Amino Acids Using Catalytic Addition of Thiol

  • 1334

    Photochemical Strategy for Radical Pathway to Access β -Amino Acid Derivatives

  • 1335

    Cyclic Tetrapeptide Synthesis via an Epimerization-Free Direct Aminolysis

  • 1336

    Total Synthesis of Cyclic Hexapeptides: Nicrophorusamides A and B

  • 1337

    Direct C–H Alkylation of Glycine Derivatives with Alkenes by Radical-Polar Crossover Reaction

  • 1338

    Cyclization of N-Propargyl-N-Sulfonyl Amino Alcohols by Silver Catalysis and Solid-Phase Applications

  • 1339

    Accessing Macrocyclic Thiolactone Peptides by Radical-Mediated Intramolecular Thiol–Ene Ligation

  • 1340

    Asymmetric N-Allylation of Amino Acids and Peptides

  • 1341

    Cobalt-Catalyzed Reductive Addition of Dehydroglycine

  • 1342

    Alkylation of Glycine Derivatives via a Combination of Single-Electron and Halogen-Atom Transfers

  • 1343

    Stereoselective Michael Addition Reaction for Synthesis of Unnatural Amino Acids

    • Flow Chemistry

  • z1345

    All PDFs of this category

  • 1345

    Flowing towards β-Silyl Amines via Energy Transfer and Hydrogen Atom Transfer

    • Erratum

  • 1346

    Erratum: Regioselective Three-Component Carboamination of Propargylic Alcohols to Access N,O-Heterocycles