DOI: 10.1055/s-00000131

Synfacts

Ausgabe 11 · Volume 20 · November 2024 DOI: 10.1055/s-014-60459

Synform

  • A165

    SYNFORM ISSUE 2024/11

    • Synthesis of Natural Products

  • z1121

    All PDFs of this category

  • 1121

    Total Synthesis of (+)-Strepsesquitriol

  • 1122

    Synthesis of (–)-Fasicularin

  • 1123

    Total Synthesis of (−)-Cyathin B2

  • 1124

    Total Synthesis of (+)-Quadrigemine H

  • 1125

    Total Synthesis of (–)-Cyctetryptomycin A and B

  • 1126

    Total Synthesis of (–)-Euphordraculoate A and (+)-Pedrolide

  • 1127

    Total Synthesis of (±)-11-O-Debenzoyltashironin

    • Synthesis of Heterocycles

  • z1129

    All PDFs of this category

  • 1129

    Ethylene Sulfate: A Two-Carbon Synthon for a Modular Synthesis of Morpholines

  • 1130

    Tandem Synthesis of 1,3-Oxazepine from 5-Benzylidine Meldrum's Acids and TosMIC

  • 1131

    Substrate-Controlled ortho-Amination of Complex (Hetero)Arene Derivatives

  • 1132

    Multi-Kilogram Synthesis of a Complex Cyclopropyl Pyrazole from (R)-Epichlorohydrin

  • 1133

    Modular Diversification to Rapidly Access Substituted 1,6-Naphthyridines

  • 1134

    Enantioselective Synthesis of 2-Oxazolidinones Using Organoselenium Catalysis

  • 1135

    Access to 1-Azabicyclo[2.1.1]hexanes as Potential Bioisosteres for 3-Substituted Pyridines

  • 1136

    Resolution of Atropisomers through Organocatalyzed Knoevenagel Reaction

  • 1137

    Modular, Sustainable Syntheses of Novel N-Hetero-cyclic Compounds through Regenerative Cyclization

  • 1138

    Versatile Two-Step Catalytic Stereoselective Approach to Chiral anti-2,4-Tetrahydrofuran Derivatives

  • 1139

    Atom-Efficient [2+2+2] Rhodium-Mediated Cycloaddition for the Synthesis of Chiral Tetrahydroindoles

  • 1140

    Synthesis of 1,2,4-Oxadiazole-5-thiones and Thioamides

  • 1141

    Facile Access to γ-Functionalized α-Amino Acid Derivatives

    • Synthesis of Materials and Unnatural Products

  • z1143

    All PDFs of this category

  • 1143

    When Cycloaddition Met Mechanochemistry

  • 1144

    A Buckybowl with a “Handle”

  • 1145

    Nitrogen-Rich Nanographene

  • 1146

    Iron-Catalyzed Aza-annulation via C(sp²)–H Activation

  • 1147

    Alternating Radical Stitching Polymerization

  • 1148

    Proton Transfer Anionic Polymerization

  • 1149

    Aromaticity Featuring a B=B Bond

  • 1150

    An Extended, Split Azulene

  • 1151

    Cyclooligomerization of Fluorene via C–H Activation

  • 1152

    A Forgotten Borole: 1-Boraindene

  • 1153

    Metal-Free Syntheses of π-Extended Triazatrinaphthylenes and 2D Materials

  • 1154

    Palladium-Catalyzed Hydroaminocarbonylative Polyaddition

    • Metals in Synthesis

  • z1155

    All PDFs of this category

  • 1155

    Silyl-Directed Borylative C–H Functionalization of Arenes

  • 1156

    Nickel-Catalyzed Cross-Coupling of Cyclic Sulfones and Grignard Reagents

  • 1157

    Mechanistic Investigation into Three-Component Carboamination

  • 1158

    Palladium-Catalyzed Synthesis of anti-Selective Cyclopropanes

  • 1159

    Markovnikov Hydroarylation via a Cobalt/Nickel Cocatalyzed Photochemically Induced System

  • 1160

    Synthesis of Functionalized Indenes via Palladium/Blue Light Catalyzed Skeletal Rearrangement

  • 1161

    Selective Functionalization of Monoactivated Bisboronates via Copper Catalysis

  • 1162

    Secondary Phosphine Oxide/Palladium-Catalyzed α-Deuteration of Pyridine C–H Bonds

  • 1163

    Benzoxazinone Synthesis via Double Alkyne Incorporation Using Gold Catalysis

  • 1164

    Palladium-Catalyzed Isomerization of Propargyl Allylic Alcohols via β-Alkynyl Elimination

  • 1165

    Negishi-Type Cross-Coupling Reaction of a CF2H Reagent and Aryl Thianthrenium Salts

  • 1166

    Synthesis of Enantioenriched Organofluorides by Nickel-Catalyzed Hydroalkylation of Fluoroalkenes

  • 1167

    Regioselective Three-Component Carboamination of Propargylic Alcohols to Access N,O-Heterocycles

  • 1168

    Asymmetric Intramolecular Hydroamination of 2,4-Dienyl Hydrazones by Pd(0)/Brønsted Acid Cocatalysis

  • 1169

    Synthesis of Chiral α-Alkyl Succinimides by Palladium-Catalyzed Migratory Hydroamidocarbonylation

  • 1170

    C(sp2)–CN Cross-Coupling by Ligand-Enabled Gold(I)/Gold(III) Redox Catalysis

  • 1171

    Synthesis of Isotopically Labelled Alkyl Aryl Ketones by Nickel-Catalyzed Carbonylative Cross-Coupling

  • 1172

    Cobalt-Catalyzed Carbonylative Cyclization of Homoallylic Alcohols and Amines

  • 1173

    Direct C(sp2)–H Arylation and Alkynylation of Allenes under Copper Catalysis via Hydrogen Atom Abstraction

  • 1174

    Aromatic Ketones as Aryl Electrophiles in Metal-Catalyzed Deacylative Cross-Coupling Reactions

  • 1175

    Stereoselective Cyclization of 1,6-Enynes via Reductive Nickel Catalysis

  • 1176

    Palladium-Catalyzed α-Arylation of α-Vinyl Boronates

  • 1177

    Asymmetric α‑Vinylation of γ‑Lactams

  • 1178

    Access to α,β-Unsaturated Carboxylic Acids by Iridium-Catalyzed Transfer Dehydrogenation

  • 1179

    Take Sulfones Instead of Carbenes: Cyclopropanation of Allylic Alcohols under Manganese Catalysis

  • 1180

    Synthesis of 2,3-Disubstituted Indoles via Palladium Catalysis

    • Polymer-Supported Synthesis

  • z1181

    All PDFs of this category

  • 1181

    Asymmetric Michael Addition Catalyzed by a Polyisocyanide-Based Porous Polymer

  • 1182

    Photocatalytic C–H Arylation of Heteroarenes with Arylamines Using Fe3O4 Nanoparticles

  • 1183

    Synthesis of Fluoroalkylated Indolines Using Molten-Salt Carbon Nitride Photocatalysts

  • 1184

    Continuous-Flow C–H Amidation of 2-Phenylpyridines Catalyzed by a Cp*Rh(III) Catalyst Supported on Silica

  • 1185

    Indole Synthesis through Intramolecular Heck Reaction with in situ Generated Pd Nanoparticles in PEG

  • 1186

    CdS Nanosheets-Catalyzed Formation of Imines and Amines by Photoreductive Coupling Reactions

  • 1187

    Mechanochemical Oxidative Heck-Type Reaction Assisted by Cyclodextrin

  • 1188

    Controlled Hydrogenation of Alkynes Using Ni2P Nanoparticles Supported on Al2O3

  • 1189

    Hydrogenation of Nitriles Using Co Nanoparticles

  • 1190

    Hydrocarboxylation of Terminal Alkenes with Formate by a ZnIn2S4 Photocatalyst

  • 1191

    RhRu Bimetallic Cluster Catalysts for Dehydrogenative Cross-Coupling of Arenes and Carboxylic Acids

    • Organo- and Biocatalysis

  • z1193

    All PDFs of this category

  • 1193

    Enzymatic Asymmetric Radical Dearomatization of Electron-Rich Arenes Towards Chiral Spirocycles

  • 1194

    Geometric Preorganization in Small-Molecule Catalysis

  • 1195

    Photocatalytic Azetidine Synthesis via Radical Strain Release of Azabicyclo[1.1.0]butanes

  • 1196

    Enantioselective Borane-Catalyzed Michael Addition of 2-Alkylbenzoxazoles to Electron-Deficient Olefins

  • 1197

    Metallomimicking Phosphorous Complex Enables Catalytic Hydrogenation

  • 1198

    Molecular Editing of Ketones through N‑Heterocyclic Carbene and Photo Dual Catalysis

  • 1199

    Heterogeneous Non-covalent Organic Framework Enables Enantio- and Periselective [6+4] Cycloaddition

  • 1200

    The Catalytic Asymmetric Polyene Cyclization of Homofarnesol to Ambrox

  • 1201

    Chiral Lewis Base Catalyzed Dynamic Kinetic Asymmetric Transformation of Chlorosilanes

    • Innovative Drug Discovery and Development

  • z1203

    All PDFs of this category

  • 1203

    A Novel Method to Incorporate 2,2-Difluoroethyl Group as a Lipophilic Hydrogen-Bond Donor

  • 1204

    Skeletal Editing of Indoles and Pyrroles Enabled by a Novel, Atomic Carbon Equivalent

  • 1205

    Enantioselective and Organocatalytic Sulfenamide S-Alkylation

  • 1206

    Amination of Base-Sensitive Aryl Bromides and Divergent Amino Alcohol Arylation Using Cu-Catalysis

  • 1207

    Process Optimization Enables Safer, Greener Synthesis of Valbenazine Ditosylate

  • 1208

    An Enantioselective Synthesis of Azabicyclo[2.1.1]hexanes, sp3-Rich Motifs for Drug Design

  • 1209

    Total Synthesis of (–)-Codeine via Cascade Double Heck Cyclization

  • 1210

    Boronate-Based Prodrugs for Oxidative Release of Drugs

  • 1211

    Novel Ru-Catalyzed Asymmetric Hydrogenation Enables 100 Kilogram-Scale Synthesis of Brivaracetam

  • 1212

    Late-Stage Pyridine Oxidation via Oxygen Walking

  • 1213

    Synthesis of meta Benzene Isosteres

  • 1214

    Derivatizing and Optimizing Neo-Clerodane through Mechanistic SAR Studies

  • 1215

    Thiopyrylium NIR-II Photosensitizer Enables Mitochondria-Localized Dual Pyroptosis and Apoptosis

  • 1216

    Merging Boryl Radical-Mediated Halogen-Atom Transfer and Copper Catalysis for the Alkylation of Amides

    • Peptide Chemistry

  • z1217

    All PDFs of this category

  • 1217

    Electron-Rich Triaryl Phosphine Mediated Electrochemical Synthesis of Peptides

  • 1218

    meso- and l,l-Diaminopimelic Acids: A Stereoselective Synthesis from α-Amino Acids

  • 1219

    Cysteine-Directed Pd-Catalyzed β-C(sp3)–H Arylation of Alanine in Linear and Cyclic Peptides

  • 1220

    Radical C–C Coupling Reaction for the Synthesis of CF3-Containing Amino Acids

  • 1221

    Synthesis of α-Amino Acids via Iron-Catalyzed 1,3-Nitrogen Migration

  • 1222

    Synthesis of Macrocyclic Peptides via Thioketalization of Cysteine-Containing Peptides

  • 1223

    Hydroalkenylations of Olefins and Styrenes Using Iridium Catalyst via Enamine Formation

  • 1224

    Synthesis of Aminonitriles by Asymmetric Strecker Reaction Using Organocatalysis

  • 1225

    Catalytic Synthesis of Unnatural α/β-Amino Acids and  -Peptides

  • 1226

    Methionine-Directed C–H Glycosylation of Peptides Catalyzed by Pd(OAc)2

  • 1227

    Palladium-Catalyzed Cinnamylation and Decinnamylation of Complex Oligopeptides

  • 1228

    Boronate Synthesis from Lys Derivatives

  • 1229

    Sequential Fluorination and Amidation of Thioesters

  • 1230

    FCDMT-Mediated Peptide Synthesis

    • Flow Chemistry

  • z1231

    All PDFs of this category

  • 1231

    Arylation of Gaseous Alkanes in Flow