DOI: 10.1055/s-00000131

Synfacts

Issue 07 · Volume 19 · July 2023 DOI: 10.1055/s-013-57728

Synform

  • A114

    SYNFORM ISSUE 2023/07

    • Synthesis of Natural Products

  • z0637

    All PDFs of this category

  • 0637

    Syntheses of (–)-Scabrolide A and (–)-Yonarolide

  • 0638

    Total Synthesis of (+)-Ineleganolide

  • 0639

    Total Synthesis of (–)-Daphnezomine A

  • 0640

    Synthesis of (±)-KB343

  • 0641

    Synthesis of (+)-Pedrolide

  • 0642

    Total Synthesis of (–)-Grayanotoxin II

  • 0643

    Synthesis of (–)-Aspidophytine

    • Synthesis of Heterocycles

  • z0645

    All PDFs of this category

  • 0645

    Aryl Radicals as XAT Promotors Enable Modular Alkyl Iodide Functionalization

  • 0646

    Synthesis of Azabicyclic Cores of the Izidine Alkaloids

  • 0647

    Ion-Paired Rhodium-Catalyzed Enantioselective Aziridination of Alkenyl Alcohols

  • 0648

    Three-Component Reaction for the Synthesis of Isoxazoles

  • 0649

    Stereoselective Synthesis of Six-to Eight-Membered Cyclic Ethers through Homologation/Metathesis

  • 0650

    A Magical Rearrangement of Aryl Peroxyoxindoles to 1,3-Benzooxazin-4-ones

  • 0651

    Cascade Reaction with Preservation of Stereochemistry for the Synthesis of Fused Cyclic Amine Systems

  • 0652

    Synthesis of Functionalized Bicyclic Tetrahydrocyclopentafuran Derivatives

  • 0653

    Operationally Simple Dearomatization of Bicyclic Azaarenes

  • 0654

    Robust Trifluoromethylation of (Hetero)arylboronic Acid Pinacol Esters

  • 0655

    Site Selective C–H Carboxylation of N-Heteroarenes via Electrochemical Reactors

    • Synthesis of Materials and Unnatural Products

  • z0657

    All PDFs of this category

  • 0657

    Pyrenylenes of Varied Size from One Pot

  • 0658

    Chiral Bowl-Shaped PAHs with Five- and Eight-Membered Rings

  • 0659

    A One-Pot Method from Six- to Seven-Membered Rings

  • 0660

    Dearomatization of Quinolines and Isoqunolines

  • 0661

    π-Extended Chiral [2.2]Cyclophanes

  • 0662

    A Chiral Calix[3]pyrrole Analogue

  • 0663

    Heptacene Analogue with Benzodi[7]annulene

  • 0664

    Pot-Economic Approach to Benzophenanthridine Alkaloids

  • 0665

    Stochastic Bullvalene Architecture Modulates Structural Rigidity in π-Rich Macromolecules

  • 0666

    Functionalizing COFs via Ugi Reaction

  • 0667

    Recyclable and Malleable Polycyanurate Thermosets

  • 0668

    A Modular Strategy for N-Doped PAHs with Nonhexagons

    • Metals in Synthesis

  • z0669

    All PDFs of this category

  • 0669

    An Asymmetric Intramolecular Heck-Type Reaction of in situ Generated Hydrazones

  • 0670

    Enantioconvergent Trifluoromethoxylation of Propargyl Sulfonates under Copper Catalysis

  • 0671

    Enantioselective Copper-Catalyzed Three-Component Synthesis of Z,Z-Multifunctional-1,5-dienes

  • 0672

    Metal-Controlled Regiodivergent Hydroamination of α-Methylene-β-Lactams

  • 0673

    Nickel-Catalyzed Asymmetric Vinylogous Addition of Silyloxyfuran to Oxindoles

  • 0674

    Cobalt-Catalyzed Hydroalkylation of Glycals for the Stereoselective Synthesis of 2-Deoxy-β-C-Glycosides

  • 0675

    Gone in 60 Seconds: Very Fast Birch Reductions under Ammonia-Free Conditions Using Ball-Milling Technique

  • 0676

    Silver-Catalyzed Formation of Benzo[d]oxepines via Ring-Expansive Addition of Diazonium Compounds

  • 0677

    Terminating the Catellani Reaction by C(sp2)–I Reductive Elimination to Access ortho-Iodobiaryls

  • 0678

    Copper/Chromium-Catalyzed Nucleophilic C(sp3)–H Addition of Alkanes to Aldehydes under Visible Light

  • 0679

    Cobalt-Catalyzed Reductive Arylation of N-Sulfonyl Imines

  • 0680

    Gold-Catalyzed Heck Reaction with Selective β-Hydride Elimination

  • 0681

    Asymmetric Metalloradical-Catalyzed Synthesis of Cyclopropane-Fused Chromanes and Chromanones

  • 0682

    Functionalized 1,4-Dihydropyridines Using Benzylamines, N,N-Dimethyl Enaminones and Copper

  • 0683

    Rhodium-Catalyzed Synthesis of Chiral trans-γ‑Lactams through Dynamic Kinetic Resolution

  • 0684

    Turning Enol Triflates into Axially Chiral Allenes by Palladium-Catalyzed Enantioselective β-H Elimination

  • 0685

    Cooperative Dihydrogen Activation by a Zinc–Anilide Complex Enables Semi-Hydrogenation of Alkynes

  • 0686

    Photoredox-Catalyzed Trifluoromethylation of C(sp2)–H Bonds with Trifluoroacetic Anhydride

  • 0687

    β-Selective C(sp3)–H Borylation of Saturated Cyclic Amines and Lactams by Cooperative Catalysis

  • 0688

    Palladium-Catalyzed Benzylic Allyl-/Allenylation of Benzyl Chlorides

  • 0689

    Sulfamidate Imine Derived 1-Azadienes: A New Class of Dipolarophiles in Pd-Catalyzed [3+2] Cycloadditions

  • 0690

    A Ligand-Controlled Stereodivergent Decarboxylative Aldol Reaction under Titanium Catalysis

  • 0691

    Z-Retentive Asymmetric Allylation of Oxindoles Using Iridium Catalysis

  • 0692

    A General Protocol for Photoinduced C(sp3)–H Functionalization under Iron Catalysis

  • 0693

    Enantioconvergent Synthesis of α-Amino Acids by Iron-Catalyzed α-C(sp3)–H Amination of Carboxylic Acids

  • 0694

    Synthesis of Functionalized Skipped Dienes via Nickel-Catalyzed Reductive Cross-Coupling

  • 0695

    Synthesis of 2,3-Disubstituted Indoles via Palladium-Catalyzed Cyclization of ortho-Alkynyl Anilines

    • Polymer-Supported Synthesis

  • z0697

    All PDFs of this category

  • 0697

    Cross-Dehydrogenative C(sp2)–N Coupling by a Cu–Co Dual-Atom Catalyst Supported on Hierarchical Zeolite

  • 0698

    N-Monomethylation of Primary Amines and Nitroarenes with Methanol Using Pd(II) Dispersed on Zn(Al)O

  • 0699

    Mechanochemical Suzuki–Miyaura Coupling Promoted by PEG-Supported Palladium Complex

  • 0700

    Reductive Amination of Aryl Ethers Catalyzed by Hf-Exchanged Montmorillonite-Supported Pd

  • 0701

    Hydroboration of Olefines with a Cobalt(0)-COF Catalyst

  • 0702

    Bodipy-Based MOFs Transformed from 1D Chain to 2D Layer as Photocatalysts Build C–B and C–C Bonds

  • 0703

    Monophosphine-Ir or -Ru Complexes in Chiral Diphosphine-Based COFs for Asymmetric Hydrogenation

  • 0704

    Photo-Induced Borylation of N-Heteroarenes with a β-Keto Enamine-Based Covalent Organic Framework

  • 0705

    Ruthenium Phosphide Nanoparticles Supported on SiO2 for Hydrogenation of Sulfur-Containing Nitroarenes

  • 0706

    Photocatalytic Oxidative Homo-Coupling of Amines by a Donor–Acceptor Mixed-Ligand MOF

  • 0707

    Synthesis of Tetrasubstituted Pyridines through Solid-Phase Truce–Smiles Rearrangement

  • 0708

    C–H Oxidation and Epoxidation of Alkenes Using a FeIII–MOF-253 Complex with O2

    • Organo- and Biocatalysis

  • z0709

    All PDFs of this category

  • 0709

    Engineered Methyltransferase-Catalyzed Terminal Prenyl Group Tail Methylation of Linear Terpenoids

  • 0710

    BINOL Catalysis Permits One-Pot Synthesis of Chiral Trifluoromethyl and Trimethylsilyl Allenols

  • 0711

    Asymmetric Conjugate Hydrocyanation of Enals via SET-Induced Umpolung

  • 0712

    Methionine Sulfoxide Reductase as an Efficient Catalyst for Kinetic Resolution of the Chiral Sulfoxides

  • 0713

    Regioselective meta-Amination of Arylamines Enabled by in situ Generated Quinone Imine Ketals

  • 0714

    Towards Efficient Synthesis of Chiral β-Amino Amides via Organocatalysis

  • 0715

    Novel C2-Symmetric Borinic Acids Expand the Scope of Boron-Based Catalysts for Asymmetric Transformations

  • 0716

    Organocatalytic Enantioselective Reductive Radical Coupling of Ketimines with Dihydropyridines

  • 0717

    Enantioselective Iminium Catalysis-Mediated Vinylcyclopropane–Cyclopentene Rearrangement

    • Innovative Drug Discovery and Development

  • z0719

    All PDFs of this category

  • 0719

    Conquering Regioselectivity Issues: Scalable Synthesis to an Alkylated 1,2,4-Triazole Building Block

  • 0720

    Synthesis of Selective HDAC11 Inhibitor with Nanomolar Potency

  • 0721

    Controlling Protein Activity with a Carboxyl Group Cage

  • 0722

    A Dearomative Cyclization Approach Enables Easy Access to Cardenolides from the Hajos–Parrish Ketal

  • 0723

    Semi-Rational Design Expedites Identification of Imine Reductases with Complementary Enantioselectivity

  • 0724

    Discovery of Haloperidol

  • 0725

    Efficient Synthesis of Ketoprofen

  • 0726

    Practical and Environmentally Friendly Manufacturing Process for Ensitrelvir, a SARS-CoV-2 Antiviral Candidate

  • 0727

    Discovery of a Potent and Orally Bioavailable Estrogen Receptor Degrader-Antagonists

  • 0728

    Synthesis of Urazolyl-Tyrosine Macrocyclic Peptides via Chemoselective Oxidative C–N Coupling

  • 0729

    Preparation of Biologically Active Peptide-Isoquinolone Conjugates

    • Peptide Chemistry

  • z0731

    All PDFs of this category

  • 0731

    C–H Functionalization for the Synthesis of Maleimide-Decorated Peptides and Macrocyclic Peptides

  • 0732

    Regioselective Fluorination of Amino Acid Derivatives

  • 0733

    Electrosynthesis of γ,δ-Unsaturated α-Amino Esters

  • 0734

    Pd-Catalyzed α-Allylation of N-Unprotected Amino Acids

  • 0735

    One-Pot Synthesis of Amnio Acids with Consecutive Tetrasubstituted Stereogenic Center

  • 0736

    Asymmetric Alkylation to Afford Tetrasubstituted Amino Acids

  • 0737

    Copper-Catalyzed Synthesis of α-Amino Acids from Primary Alcohols

  • 0738

    Selective Deprotection of tert-Butyl Ester Groups in N-Boc-Protected Amino Acid tert-Butyl Esters

    • Flow Chemistry

  • z0739

    All PDFs of this category

  • 0739

    Enantioselective Synthesis of α-Alkylated Aldehydes Using Continuous Flow Chemistry and Visible Light