DOI: 10.1055/s-00000131

Synfacts

Issue 04 · Volume 16 · April 2020 DOI: 10.1055/s-010-46169

Synform

  • A51

    SYNFORM ISSUE 2020/04

    • Synthesis of Natural Products and Potential Drugs

  • z0371

    All PDFs of this category

  • 0371

    Synthesis of an Indoleamine-2,3-dioxygenase-1 (IDO1) Inhibitor

  • 0372

    Total Synthesis of (–)-Cymoside

  • 0373

    Total Synthesis of (+)-Corymine and (–)-Deformylcorymine

  • 0374

    Synthesis of (–)-FD-594

  • 0375

    Total Syntheses of ent-Kaurane Diterpenoids

  • 0376

    Synthesis of Aztreonam

  • 0377

    Total Synthesis of Tetrodotoxin

  • 0378

    Synthesis of Simurosertib (TAK-931)

  • 0379

    Synthesis of (–)-Pepluanol B

  • 0380

    Synthesis of BMS-986260

  • 0381

    Synthesis of (±)-Saudin

    • Synthesis of Heterocycles

  • z0383

    All PDFs of this category

  • 0383

    2-Arylpiperidines by Palladium-Catalyzed Addition of Arylboronic Acids to Acylated 2-Hydroxypiperidines

  • 0384

    Synthesis of Phosphorylpyrroloindoles by Photocatalytic Phosphinoylation/Cyclization Reactions

  • 0385

    Synthesis of Thiochromenes by Palladium-Catalyzed Ring Opening of Cyclopropyl Thioethers

  • 0386

    Regioselective Synthesis of Polyfluorinated o-Hydroxyacetophenones

  • 0387

    Chemodivergent and Enantiospecific Synthesis of Benzazepines and Allyl Fluorides

  • 0388

    Organocatalyzed Synthesis of Fully Substituted Furans from Ynamides and Quinoxaline N-Oxides

  • 0389

    Diastereoselective De Novo Synthesis of Functionalized Piperidines

  • 0390

    Construction of Highly Substituted Furans and Thiophenes with Sulfur Ylides

  • 0391

    C(sp3)–H Functionalization of Aliphatic Acids through β-Lactonization

  • 0392

    Asymmetric Copper-Catalyzed Synthesis of Dihydrobenzofuran-3-ols

  • 0393

    Palladium(II)-Catalyzed Synthesis of Tribenzo[b,d,f]azepines

  • 0394

    Three-Component Synthesis of 3-(Trifluoromethyl)pyrazoles

  • 0395

    Base-Promoted Annulations in the Synthesis of Ring-Fused N-Substituted-4-Quinolinones

    • Synthesis of Materials and Unnatural Products

  • z0397

    All PDFs of this category

  • 0397

    Approaching a Pyridine by Aza-APEX

  • 0398

    All Aboard the EBXpress to Dithioalkenes

  • 0399

    Put Phosphorus in Your Rhodamine

  • 0400

    From Simple to Complex: One-Pot Synthesis of Dimeric Pyrrolo-Fused Isoquinolines

  • 0401

    Spin Me Right Round: Spirocyclic Organic Electronic Materials

  • 0402

    Fountain of Pyrenes

  • 0403

    Lighting Up Helicenes

  • 0404

    Small Helicenes, Big Deal

  • 0405

    Party of Rotaxanes

  • 0406

    Ion Pair Receptors: Bambusuril–Crown Ether Conjugates

  • 0407

    ‘A One and A Two’: Orchestrating Polymer Backbone Breakdown

  • 0408

    Expansion of Coumarins by One-Pot Synthesis

    • Metals in Synthesis

  • z0409

    All PDFs of this category

  • 0409

    Bismuth Redox-Catalyzed Fluorination of Arylboron Reagents

  • 0410

    A Diastereo- and Enantioselective Copper-Catalyzed Allylation of Imines Using Allylic gem-Diboron Reagents

  • 0411

    Palladium-Catalyzed γ-C(sp3)–H Bond Activation of Tertiary Alkyl Amines

  • 0412

    Coupling Reactions of Aldehydes and Hydrocarbons

  • 0413

    Synthesis of Conjugated 1,3-Diynes

  • 0414

    Aryl Thioether Metathesis under Nickel Catalysis

  • 0415

    Enantioselective Preparation of Propargyl Amides

  • 0416

    Axially Chiral 2,3-Disubstituted Indoles via Palladium-Catalyzed Enantioselective Cacchi Reaction

  • 0417

    Copper-Catalyzed Coupling of Remote C(sp3)–H Bonds with Terminal Alkynes

  • 0418

    meta-Selective Inverse Sonogashira Coupling

  • 0419

    Nickel-Catalyzed Carboxylation of Arylsulfonium Salts Using CO2

  • 0420

    Palladium-Catalyzed Asymmetric Cycloadditions

  • 0421

    C–H Functionalization of Alkenes

  • 0422

    Enantioselective Rhodium-Catalyzed Hydroformylation of α-Substituted Acryl Acid Derivatives

  • 0423

    Photocatalytic Umpolung Strain-Release Amino-Functionalization of [1.1.1]-Propellanes

  • 0424

    Transthioetherification of Aryl Halides with Thioethers or Thioesters under Palladium Catalysis

  • 0425

    Stereodivergent Allylic Alkylation/Fluorination of Acyclic Ketones

  • 0426

    Dual Catalysis: Photoredox/Chromium-Catalyzed Dialkylation of 1,3-Dienes

  • 0427

    Chromium/Iridium-Photoredox Dual-Catalyzed Formal Addition of α-Amino Carbanions to Carbonyls

  • 0428

    Hydroamination of Alkenes

  • 0429

    Radical Cascade Synthesis of Azoles

  • 0430

    Nickel-Catalyzed Reductive Acylation of Aliphatic Amines

  • 0431

    Intermolecular Palladium-Catalyzed Atropo-Enantioselective C–H Arylation of Heteroarenes

  • 0432

    Synthesis of 1,3-Dienes by a Photoinduced C(sp2)−H/C(sp2)−H Cross-Coupling of Alkenes

  • 0433

    Fused Tricyclic Hydronaphthofurans through Rhodium-Catalyzed Desymmetrization

  • 0434

    Scandium-Catalyzed Enantioselective C–H Transfer Across an Alkene

  • 0435

    Low Catalyst Loading: Rhodium(II)-Catalyzed Asymmetric Cyclopropanation

  • 0436

    Photoredox-Catalyzed Benzylic C–H Activation and Coupling with Aldehydes

  • 0437

    The Corey–House Reaction: An Early Transition-Metal-Mediated Cross-Coupling

    • Polymer-Supported Synthesis

  • z0439

    All PDFs of this category

  • 0439

    Photocatalytic C–H Alkylation of Quinoxalin-2-ones on a Covalent Organic Framework

  • 0440

    Palladium/Alumina-Catalyzed Decarbonylative Aldol Condensation of Aldehydes

  • 0441

    Photocatalytic Oxidative Coupling of Benzylamines on a Hydrazone-Based Covalent Organic Framework

  • 0442

    A Zirconium–Tannin Hybrid Catalyst for Meerwein–Ponndorf–Verley Reduction

  • 0443

    Reductive Amination of 5-(Hydroxymethyl)furfural on Immobilized Palladium Nanoparticles

  • 0444

    C–C, C–O, C–S, and C–N Bond Formation from Diazo Compounds on Mesoporous Silica-Supported Triflic Acid

  • 0445

    Silver Nanoparticle Catalyzed Selective Reduction of Nitro Compounds and Nitriles

  • 0446

    Aza-Semipinacol Rearrangement Catalyzed by Graphene Oxide

  • 0447

    Flow Esterification on a Second-Generation m-Phenolsulfonic Acid–Formaldehyde Resin Catalyst

  • 0448

    Reduction of Aryl Ketones and Aldehydes to Hydrocarbons Catalyzed by Palladium/Carbon

  • 0449

    CuMoO4 Nanoparticles-Catalyzed Cross-Coupling of Aryl Halides with Thiols

  • 0450

    One-Pot Sequential Cross-Aldol Condensation/Aza-Michael Addition on Graphene Oxide

  • 0451

    Dehydrogenation of NH–NH Bonds Catalyzed by Ni–Fe Supported on N-Doped Carbon from Chitosan

    • Organo- and Biocatalysis

  • z0453

    All PDFs of this category

  • 0453

    Pot-Economic Organocatalytic Asymmetric Synthesis of the Corey Lactone

  • 0454

    Superbase-Catalyzed Enantioselective Aldol Addition of Aryl Ketones to α-Fluorinated Ketones

  • 0455

    A Modified Tripeptide Catalyst Changes Conventional Diastereoselectivity in Michael Additions

  • 0456

    Organic Single-Electron Reductants Permit Photocatalytic Borylation of C–O, C–N, and C–X Bonds

  • 0457

    N-Functionalized Azaheterocycles through PIII/PV=O-Catalyzed Cascade Synthesis

  • 0458

    NHC-Catalyzed Generation of p-Quinodimethanes through ε-Umpolung: Nucleophilic Addition to Ketones

  • 0459

    Two Distinct Hydrogen Atom Transfer Steps Permit Selective Epimerization of Pyranose Frameworks

  • 0460

    NHC-Catalyzed Umpolung Approach Toward Heteroaryl Ynones

  • 0461

    Reductive Electrophotocatalysis

    • Chemistry in Medicine and Biology

  • z0463

    All PDFs of this category

  • 0463

    RIBOTACs – Targeted Degradation of RNA

  • 0464

    Stronger Together!

  • 0465

    Protein Modification by Cope Rearrangement

  • 0466

    Potent and Selective Acid Sphingomyelinase Inhibitors with Antidepressant Activity

  • 0467

    Replacing HN3 with Nitromethane for Schmidt-Type Formation of Amides and Nitriles

  • 0468

    Lasonolide A is a Prodrug Activated by LDAH, a Serine Hydrolase

  • 0469

    PEP-K: A New Reagent for the O-Phosphorylation of Alcohols

  • 0470

    Modular, Targeted IDO Inhibitor for Cancer Immunotherapy

  • 0471

    A Potential anti-Pertussis Vaccine Based on Lipopolysaccharide Endotoxins of B. pertussis

  • 0472

    A Carbapenemase Probe that Switches on the Light

  • 0473

    Cyclic Naphthoquinone Imine Based Antagonists of the RIG-I Innate Immune Receptor

  • 0474

    Optical Control of CENP-E Function

  • 0475

    A Classic Way of Forming Amide Bonds

    • Peptide Chemistry

  • z0477

    All PDFs of this category

  • 0477

    Boronic Acid Catalyzed Dehydrative Peptide Synthesis

  • 0478

    Phase-Transfer-Catalyzed Enantioselective α-Trifluoromethylthiolation

  • 0479

    Stereoselective Synthesis of β-Amino Acid Precursors by Organocatalysis

  • 0480

    Copper-Catalyzed [3+1] Cycloaddition to Form Substrates for α-Amino Acid Synthesis

  • 0481

    Synthesis of Selenocystine-based Peptides through Cyclization Reactions

  • 0482

    Copper-Catalyzed Synthesis of Cyanated Peptides

  • 0483

    Stereoselective Synthesis of Unnatural α-Amino Acids

  • 0484

    Palladium-Catalyzed N-Arylation of Amino Acids and Ketoxime Peptide Ligation

  • 0485

    Synthesis of α-Quaternary Chiral Amino Acids by Palladium-Catalyzed Arylation

  • 0486

    Synthesis of Fmoc-Aminoacyl‑N‑alkylcysteine Dipeptides by Using the Ugi Reaction

  • 0487

    Solid-State Synthesis of a β-Turn Mimetic

    • Flow Chemistry

  • z0489

    All PDFs of this category

  • 0489

    Synthesis of Biaryl Compounds in Flow via a Lithiation, Borylation, Suzuki–Miyaura Cross-Coupling Pathway

  • 0490

    Ferrocenyl Azide Synthesis via Halogen–Lithium Exchange in Continuous Flow

  • 0491

    Acylation with Grignard Reagents in Continuous Flow