DOI: 10.1055/s-00000131

Synfacts

Issue 10 · Volume 10 · October 2014 DOI: 10.1055/s-004-27730

Synform

A127
SYNFORM ISSUE 2014/10

Synthesis of Natural Products and Potential Drugs

z1003
All PDFs of this category
1003
Synthesis of Tetrahydrolipstatin
1004
Total Synthesis of (+)-Procyanidin A2
1005
Total Synthesis of (+)-Cavicularin
1006
Synthesis of Macrocyclic Protease Inhibitors
1007
Synthesis of Sitagliptin
1008
Synthesis of Hydroxyphthioceranic Acid
1009
Total Syntheses of Spirooliganones A and B
1010
Syntheses of Spirooliganones A and B
1011
Synthesis of Gracilamine
1012
Synthesis of Paroxetine
1013
Synthesis of (–)-Crinipellin A
1014
Synthesis of Synosutine via Asymmetric Cyclopropanation

Synthesis of Heterocycles

z1015
All PDFs of this category
1015
Stereoselective Synthesis of trans-Oxazolidinones via C–H Oxidation
1016
CF3-Substituted Pyrazolines and Pyrazoles via Huisgen Cycloaddition
1017
Manganese-Mediated Coupling Approach to Fused Lactone-Pyrrolidinones
1018
1,3-Carbonyl Transposition of Ynones in the Context of Heterocyclic Chemistry
1019
Synthesis of 1,3-Disubstituted Pyrimido-pyrimidinedithiones
1020
Pyrrolideines via Cycloaddition of Silyl Ketene Acetals to Metallocarbene Precursors
1021
Mild C–H Activation of Tethered Alkynes for the Synthesis of 3,4-Fused Indoles
1022
Pyrroloquinolinones by Cascade Nitration–Cyclization of 1,7-Enynes
1023
Bisheterocycles via Rh(III)-Catalyzed C–H Activation–1,3-Diyne Coupling Route
1024
Isoindoloquinazolinones by Palladium Catalysis
1025
Synthesis of Various Thia-2H-indazoles via the Davis–Beirut Reaction
1026
One-Pot Synthesis of Fluorinated Thiadiazolo[3,2-a]pyrimidin-7-ones
1027
Safe and Scalable Preparation of 2-Nitropyrroles
1028
Phenanthridinones via Benzyne Intermediates Using Palladium Catalysis

Synthesis of Materials and Unnatural Products

z1029
All PDFs of this category
1029
Simple Synthesis of Substituted Polyheteroaromatic Compounds
1030
Cyclotetramerization of a BN-Aryne
1031
No Catalyst, No Pentasubstituted Problem
1032
Fluoride’s Foray into Transition-Metal Territory
1033
Let There Be Light: Nanoporous Two-Dimensional Polymer by Photopolymerization
1034
One π-Allylnickel Initiator, Many Block Copolymers
1035
Fluorous Acrylates Catalytically from CO, Alkynes, and Fluorous Alcohols
1036
Rearrange for a ‘U’-seful Change
1037
Come On, Let’s Do the Twist
1038
Taming Heavy Grignard Reagents: Intramolecular C–F and C–H Bond Cleavage
1039
Electron-Deficient, but the Stability is Magnificent
1040
Independent Dual-Switching Colors from Dithienylethene/Dithienylpyrrole

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z1041
All PDFs of this category
1041
Ruthenium-Catalyzed Synthesis of Z-Olefins from Alkynes and Primary Alcohols
1042
Asymmetric Arylation of β,γ-Unsaturated α-Keto Amides
1043
Asymmetric Synthesis of Furanones via Copper-Catalyzed Conjugate Addition
1044
Rhodium-Mediated Arylative 1,2-Addition Providing Chiral Thiadiazolines
1045
Nickel-Catalyzed Enantioselective Henry Reaction
1046
Silver-Catalyzed Asymmetric Aldol Reaction Using Alkenyl Trihaloacetates
1047
Copper–Lewis Acid Catalyzed Synthesis of Dihydroquinolones
1048
Asymmetric Fluorination and Hydroxylation via Iron Catalysis
1049
Catalytic Asymmetric Nitroaldol Reaction Using Continuous-Flow Technique
1050
Copper-Catalyzed Asymmetric exo′-Selective [3+2] Cycloaddition
1051
Enantioselective Carbonyl Carboacylation Initiated by C–C Bond Activation
1052
Six-Membered N-Heterocycles via Enantioselective Hydroacylation
1053
Rhodium-Catalyzed Enantioselective Synthesis of Allylic Sulfones
1054
Synthesis of All-Carbon Quaternary Stereocenters via Copper-Catalyzed N-Arylation
1055
Ruthenium-Catalyzed Asymmetric Addition of Malononitrile to α,β-Unsaturated Ketones
1056
Stereoselective Synthesis of α-Amino Aldols from Terminal Alkynes
1057
Copper-Catalyzed Intramolecular Propargylic Amination
1058
Enantioselective Hydrogenation of α,β-Disubstituted Nitroalkenes
1059
Copper-Catalyzed Stereoselective Reactions of B2(pin)2, 1,3-Enynes, and Aldehydes
1060
Enantiospecific Ligand-Free Cross-Coupling of Ammonium Triflates and Boronic Acids
1061
Direct Amination of β-Keto Esters Employing Nitrosocarbonyl Compounds
1062
Scandium-Catalyzed Enantioselective Carboannulation with Allylsilanes
1063
Diastereoselective Rhodium-Catalyzed Hydroamination of N-Allyl Imines
1064
Enantioselective Palladium-Catalyzed Decarboxylative Protonation of Carbazolones
1065
Synthesis of 3,4-Disubstituted Hexahydro-1H-furo[3,4-c]pyran Derivatives
1066
Cobalt-Mediated Darzens Reaction Providing Spiro-epoxyoxindoles
1067
Copper-Catalyzed Asymmetric Formal [3+2] Cycloaddition to Dihydrofurans

Metal-Mediated Synthesis

z1069
All PDFs of this category
1069
Synthesis of Pentafluoroethyl Copper
1070
Iron-Catalyzed Cross-Coupling of Alkyl Electrophiles with B2pin2
1071
One-Step Preparation of Potassium Acyltrifluoroborates
1072
Copper-Mediated Nucleophilic 18F Fluorination
1073
Radical- and Nonradical Mediated Hydro-stannylation of Propargylic Alcohols
1074
Reductive Cross-Coupling of Borazonaphthalenes
1075
Asymmetric Palladium-Catalyzed Allylic Substitution Using Dialkylzinc Reagents
1076
Asymmetric Addition of Lithium Acetylides
1077
Addition of Carbamoyl Anions to Nitrones
1078
α-Allyl-α-aryl α-Amino Esters by Tandem N-Alkylation–π-Allylation
1079
Cross-Coupling between Alkenylboronic Acids and N-Pivaloyloxylamides
1080
Base-Mediated Silylative Cyclopropanation
1081
Silver-Catalyzed Hydroboration of Alkynes
1082
Cobalt-Mediated [2+2+2] Cycloisomerization
1083
Copper-Catalyzed Trifluoromethylarylation

Organo- and Biocatalysis

z1085
All PDFs of this category
1085
Enantioselective Organo-Photocatalysis with Bi2O3 and Bi2S3
1086
NHC-Catalyzed Annulations of Aza-o-Quinone Methides and Carboxylic Acids
1087
Photoredox Organocatalytic Addition of Inorganic Acids to Styrenes
1088
[3+2] Coupling of Indoles with Quinone Monoimines Catalyzed by TRIP
1089
NHC-Catalyzed Michael Addition–Formal [2+2] Aldol Lactonization of Enals
1090
Phosphine-Catalyzed Anti-Carboboration of Alkynoates
1091
Thiyl Radical Catalyzed Enantioselective Cyclizations
1092
Regioselective Synthesis of Substituted Triazoles via Organo-Click Chemistry
1093
Enantioselective Synthesis of Tocopherols Through Oxidative Cyclization
1094
Aminocatalytic Desymmetrization of N-Arylmaleimides
1095
A Tailor-Made Enzyme for the Enantioselective Synthesis of (S)-Benzoins
1096
Imidodiphosphate-Catalyzed Desymmetrization of Bicyclic Bislactones
1097
Asymmetric Oxidation with P450tol Monooxygenase

Polymer-Supported Synthesis

z1099
All PDFs of this category
1099
Solid-Phase Synthesis of Peptoid-Like Oligomers Containing Diketopiperazine Units
1100
Hydrophobic Pd/SiO2@Mesoporous Silica for Oxidation Reactions
1101
Oxidation of Benzylic C–H Bonds with ­HKUST-1@Fe3O4
1102
Azobenzenes via Hydrogenative Coupling of ArNO2 Using a Gold Catalyst
1103
The Mizoroki–Heck Reaction Using Palladated Rasta Resin
1104
Pt/Cs2.5H0.5PW12O40-Catalyzed Hydrodeoxygenation
1105
Synthesis of Quinazolines with CuO Nanoparticles
1106
Synthesis of Imidazo[1,2-a]pyridines Using a Copper Terephthalate MOF
1107
Hydroxylation of Aryl Iodides with Cu-g-C3N4
1108
Aminolysis of Aryl Esters with Tertiary Amines Using Supported Gold NPs
1109
Dehydrogenation of Hydrazo Compounds Using a Graphene Catalyst
1110
Selective Reduction of Halogenated Nitroarenes Using Pd/C
1111
Intramolecular C–H Amination with Palladium Nanoparticles
1112
The Strecker Reaction Catalyzed by Magnetic Solid Sulfonic Acid
1113
Epoxidation with CuPcS Nanocomposites
1114
Synthesis of N1-Arylbenzotriazoles Using SAPd

Erratum

1115
Michael Addition–Reductive Lactamization Route to 5-Alkyl-5-aryl-γ-lactams