DOI: 10.1055/s-00000131

Synfacts

Issue 11 · Volume 9 · November 2013 DOI: 10.1055/s-003-25842

Synform

  • A132

    SYNFORM ISSUE 2013/11

    • Synthesis of Natural Products and Potential Drugs

  • z1141

    All PDFs of this category

  • 1141

    Synthesis of (–)-Aspidospermidine, (–)-Tabersonine, and (–)-Vincadifformine

  • 1142

    Synthesis of Hainanolidol and Harringtonolide

  • 1143

    Total Synthesis of Scholarisine A

  • 1144

    Formal Synthesis of (R)-Flurbiprofen

  • 1145

    Synthesis of MK-5172

  • 1146

    Synthesis of XL228

  • 1147

    Synthesis of Sergliflozin Analogues

  • 1148

    Synthesis of (+)-Crotogoudin

  • 1149

    Total Synthesis (±)-Agelastatin A

  • 1150

    Synthesis of (+)-Ingenol

  • 1151

    Synthesis of MK-3207

  • 1152

    Total Synthesis of (±)-Actinophyllic Acid

    • Synthesis of Heterocycles

  • z1153

    All PDFs of this category

  • 1153

    Organocatalytic Route to 2,3,4,6-Tetra- and 2,3,4,5,6-Pentasubstituted Pyridines

  • 1154

    Synthesis of 6H-Benzo[c]chromen-6-ones via Carbonylative C–H Cyclization

  • 1155

    C–H Activation Route to C-4 Substituted Isoquinolones

  • 1156

    Rh/Pd-Catalyzed Synthesis of Aza-Dihydrodibenzoxepines

  • 1157

    Efficient Borane-Catalyzed cis-Selective Reduction of 2,6-Disubstituted Pyridines

  • 1158

    1,3-Dipolar Cycloaddition Route to Pyrrolo-[3,4-c]pyrrole-1,3-diones

  • 1159

    General Strategy for the Synthesis of Cyclopropane-Fused Heterocycles

  • 1160

    Heteroannulation Route to 2-Hetarylbenzo-thiazoles through Redox Coupling

  • 1161

    Asymmetric α-Arylation Route to 5,5-Disubstituted Hydantoins

  • 1162

    Ionic Liquid Promoted Synthesis of Substituted Benzofurans

  • 1163

    Pd(II)-Catalyzed C–H Activation Route to Indolines

  • 1164

    Synthesis of Cytotoxic Fluorinated 1,2,4-Triazoles

  • 1165

    Intramolecular Acylative Coupling Approach to Dibenzo[b,e]azepin-11-ones

  • 1166

    Synthesis of Pyridazines and Their Fused Derivatives from 1,3-Diketones

  • 1167

    Synthesis of Dihydropyrimidin-4-ones from Propargyl Amides and Sulfonyl Azides

    • Synthesis of Materials and Unnatural Products

  • z1169

    All PDFs of this category

  • 1169

    Copper is the Key to C–C Cross-Coupling of C1-Carboranes

  • 1170

    A New Twist on Azahelicene

  • 1171

    A New Type of Nanocarbon Material

  • 1172

    A Spirocycle Feast

  • 1173

    Taking Rylene Diimide Dyes to New Lengths

  • 1174

    Complex Cage Architecture Incorporating All Ring Sizes from Three to Seven

  • 1175

    Rationally Designing a Polymerization Catalyst for Electron-Deficient Monomers

  • 1176

    A ‘Ring Walk’ in the Park: Pentafulvenes Rearrange at Room Temperature

  • 1177

    Octiarenes from Unfunctionalized Ternaphthalenes and Substituted Benzenes

  • 1178

    Atom-Economic Syntheses of Thiophenes and Bithiophenes

  • 1179

    Rhodium Cascade Leads to Functionally Rich Acridines and Phenazines

  • 1180

    Extensive Functionalization of Butyl Rubber

  • 1181

    Diazadithia[7]helicenes

    • Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

  • z1183

    All PDFs of this category

  • 1183

    Asymmetric Hydrogenation of Indolizines and 1,2,3-Triazolo[1,5-a]pyridines

  • 1184

    Ru-Catalyzed Asymmetric Hydrogenation of Flavones and Chromones

  • 1185

    Asymmetric Ni-Catalyzed Hydrocarbamoylation of Alkenes

  • 1186

    Asymmetric Hydrogenation by a BridgePHOS-Ligated Pd Complex

  • 1187

    Rh-Catalyzed Asymmetric Hydrogenation of Nitroalkenes

  • 1188

    Iron-Catalyzed Enantioselective Synthesis of Sulfimides

  • 1189

    Enantioenriched Bicyclic Alcohols via Transannular Ketone-Ene Reaction

  • 1190

    Ruthenium-Catalyzed Asymmetric Hydrogenation of tert-Alkyl Ketones

  • 1191

    Electrophilic α-Oxygenation Reaction of β-Keto Esters

  • 1192

    Synthesis of Bicyclic Ureas via Palladium-Catalyzed Carboamination

  • 1193

    Ir-Catalyzed Dehydrogenative Alkene Silylation

  • 1194

    Chiral α‑Amino Phosphonates via Rh(I)-Catalyzed Enantioselective 1,4-Addition

  • 1195

    Palladium-Catalyzed Desymmetrization of Carbon Nucleophiles

  • 1196

    Pd-Catalyzed Alkylation of Unactivated β-C(sp3)–H Bonds of α-Amino Acids

  • 1197

    Regio- and Diasteroselective Ru-Catalyzed Hydrohydroxylation

  • 1198

    Nickel-Catalyzed Asymmetric Arylation of Pyridinium Ions

  • 1199

    Asymmetric Intermolecular Cyclization via Pd-Catalyzed Heck Reaction

  • 1200

    Catalyst Controlled C–O versus C–N Allylic Functionalization of Olefins

  • 1201

    Rh-Catalyzed Three-Component Reaction of Diazo Compounds

  • 1202

    Synthesis of Chiral Allenoates by an ECNU-Phos-Ligated Pd Complex

  • 1203

    Pd-DAAA Reaction: Construction of Vicinal Quaternary Stereocenters

  • 1204

    Iron(II)-Catalyzed Asymmetric Aminohydroxylation of Indoles

  • 1205

    Synthesis of Enantioenriched, Functionalized Secondary Alcohols

  • 1206

    Ti-Catalyzed Asymmetric Pinacol Coupling of Aromatic Aldehydes

  • 1207

    Enantioselective Cu(II)- and Amine-Catalyzed α-Alkenylation of Aldehydes

  • 1208

    Relay Catalysis: Asymmetric Synthesis of anti-Homoallylic Alcohols

  • 1209

    Cu-Catalyzed Asymmetric Borylative Cyclization of 1,6-Enynes

  • 1210

    Stereoselective Ni-Catalyzed Cycloadditions and Alkenylative Cyclizations

  • 1211

    Asymmetric Hydrogenation of Dienamides En Route to Chiral Amines

  • 1212

    BiCl3-Promoted Synthesis of Perhydrofuro[2,3-b]pyrans and -furans

    • Metal-Mediated Synthesis

  • z1213

    All PDFs of this category

  • 1213

    Trifluoromethylation of Arenediazonium Tetrafluoroborates

  • 1214

    Bi(V)-Mediated Coupling of Thioglycosides with Glycosyl Acceptors

  • 1215

    Pd-Catalyzed Enantioselective Synthesis of α-(Trifluoromethyl)arylmethylamines

  • 1216

    Ru-Catalyzed Electrophilic Borylation of Heterocycles with Pinacolborane

  • 1217

    Highly Enantio- and Diastereoselective Aldol Reactions of N-Acryloylmorpholine

  • 1218

    Lithium-Mediated Synthesis of N-Substituted 2-Haloacetamides

  • 1219

    Direct Pd-Catalyzed Cross-Coupling of Organolithium Compounds

  • 1220

    Isocoumarine Synthesis via Tandem Michael Addition/Cyclization Reaction

  • 1221

    Enantioconvergent Couplings of Racemic α-Zn-Pyrrolidines with Alkyl Halides

  • 1222

    Asymmetric Br–Li Exchange Reaction in the Synthesis of Natural Products

  • 1223

    Fe-Catalyzed Reduction of Esters to Aldehydes

  • 1224

    Reductive Cleavage of Aryl O-Carbamates to Phenols

  • 1225

    Preparation of Fluoroalkenes by the Shapiro Reaction

  • 1226

    Rh-Catalyzed Boron Arylation of 1,2-Azaborines

  • 1227

    Organoaluminum-Mediated Interrupted Nazarov Reaction

    • Organo- and Biocatalysis

  • z1229

    All PDFs of this category

  • 1229

    Photochemical α-Alkylation of Aldehydes

  • 1230

    Intramolecular Oxa-Michael Reaction of α,β-Unsaturated Amides and Esters

  • 1231

    Brønsted Acid Catalyzed Enantioselective Cross-Dehydrogenative Coupling

  • 1232

    Phase-Transfer Organocatalytic Deracemization

  • 1233

    Organocatalytic Asymmetric Mannich-Type Reaction of Aminals

  • 1234

    Boronic Acid Catalyzed Hydrosilylation of Amides to Amines

  • 1235

    Enantioselective Aza-Diels–Alder Reaction of Azadienes with Enecarbamates

  • 1236

    Kinetic Resolution of Secondary Alcohols by Chiral Phosphoric Acids

  • 1237

    Silanediols as a New Type of Anion-Binding Organocatalysts

  • 1238

    Procedure-Controlled Enantioselectivity Switch in 2‑Oxazolidinone Synthesis

  • 1239

    Arylation of Diazoesters by a Transient N–H Insertion Organocascade

    • Polymer-Supported Synthesis

  • z1241

    All PDFs of this category

  • 1241

    Pd-Catalyzed Cross-Coupling Using Polymer-Supported Siloxane

  • 1242

    Preparation of Cyclic Carbonates with N-Heterocyclic Carbene–Ag Catalysts

  • 1243

    Direct Synthesis of Cyclohexylanilines from Nitrobenzenes with Pd/C

  • 1244

    N-Arylation of Amines Using a Cu–Mn Bimetallic Solid Catalyst

  • 1245

    Nanoporous Au-Catalyzed Oxidative N-Formylation of Amines with MeOH

  • 1246

    Heck and Sonogashira Reactions Using Pd-Fe3O4 Nanocrystals

  • 1247

    A Solid Base Catalyst for the Synthesis of Isatinylidene Rhodamines

  • 1248

    Preparation of Silyl Isocyanates Using Au/Al2O3

  • 1249

    FeNPs-Catalyzed C–Se and C–Te Bond Formation Reactions

  • 1250

    Suzuki–Miyaura Coupling with Cross-Linked Imidazolium/Silica-Pd Catalyst

  • 1251

    Friedel–Crafts Reaction Catalyzed by Urea-Postmodified MOF

  • 1252

    Polymer-Supported Ru–dm-Pheox for Quinones Synthesis

  • 1253

    Preparation of Tetrasubstituted Pyridines with Amberlite IRA-400 (OH–)

  • 1254

    A Metal-Organic Framework for the Diels–Alder Reaction