Synfacts
Ausgabe 11 · November 2012
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Ausgabe
Synform
A107
SYNFORM
ISSUE 2012/11
FREIER ZUGRIFF
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Synthesis of Natural Products and Potential Drugs
z1163
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PDF (452 kb)
1163
Synthesis of (+)-Artemisinin
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PDF (141 kb)
1164
Second-Generation Synthesis of Sulopenem
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PDF (123 kb)
1165
Third-Generation Synthesis of Sulopenem
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HTML
PDF (143 kb)
1166
Convergent Total Syntheses of Callipeltosides A, B, and C
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HTML
PDF (108 kb)
1167
Synthesis of (–)-9-
epi-
Presilphiperfolan-1-ol and (–)-Presilphiperfolan-1-ol
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PDF (131 kb)
1168
Synthesis of an H
3
Antagonist
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PDF (104 kb)
1169
Synthesis of MK-4256
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PDF (123 kb)
1170
Synthesis of a Hydroxamic Acid LpxC Inhibitor
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PDF (112 kb)
1171
Synthesis of (+)-Ponapensin and (+)-Elliptifoline
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PDF (127 kb)
1172
Synthesis of Methopholine
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PDF (132 kb)
1173
Total Synthesis of (+)-Marinomycin A
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PDF (101 kb)
1174
Synthesis of a BACE1 Inhibitor
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PDF (120 kb)
1175
Synthesis of (–)-Jiadifenin
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PDF (122 kb)
1176
Synthesis of AM-8553
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PDF (122 kb)
1177
Second-Generation Synthesis of (–)‑Aplyviolene
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PDF (121 kb)
1178
Synthesis of an IGF-1R Modulator
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PDF (102 kb)
1179
Synthesis of Thiazesim
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PDF (136 kb)
Synthesis of Heterocycles
z1181
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PDF (322 kb)
1181
Rhodium/Lewis Acid Catalyzed Cascade Synthesis of Tetrahydropyridazines
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PDF (107 kb)
1182
Heterocycles via Use of 2-Heteroaryl-2-(tetrahydrofuranyliden)acetonitriles
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PDF (127 kb)
1183
Practical Brønsted Acid Mediated Synthesis of Coumarins from Allenes
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HTML
PDF (104 kb)
1184
Cu-Catalyzed Synthesis of Furoindolines from Tryptophols
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PDF (102 kb)
1185
Synthesis of Isoindolinones by an Asymmetric Aza-Wacker-type Cyclization
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PDF (120 kb)
1186
Silver-Catalyzed Heteroannulation Route to 1-Aminoisoquinolines
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PDF (97 kb)
1187
One-Pot Gold-Catalyzed Synthesis of Azepino[1,2-
a
]indoles
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PDF (123 kb)
1188
Cascade Synthesis of 3-Pyrrolines by a Heck–Aza-Michael Reaction
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PDF (115 kb)
1189
Expedient Route to Complex Alkaloids through Pd(II)-Catalyzed Indole C-2 Alkylation
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PDF (107 kb)
1190
Synthesis of Iodotriazoles Using in Situ Generated Electrophilic Triiodide
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HTML
PDF (102 kb)
1191
One-Pot Asymmetric Synthesis of 4-Hydroxypyrazolidines from Aldehydes
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HTML
PDF (133 kb)
1192
Direct C-2 Pyridine C–H Olefination
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HTML
PDF (101 kb)
Synthesis of Materials and Unnatural Products
z1193
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1193
Efficient, Non-Toxic Polylactide Synthesis
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PDF (101 kb)
1194
Synthesis of New Ladder Diboroles
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PDF (100 kb)
1195
Ketenimine Intermediates in the Pot
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PDF (91 kb)
1196
Cycloparaphenylenes by the Gram
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PDF (102 kb)
1197
Iterative Synthesis of Polyynes
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PDF (94 kb)
1198
Gram-Scale Synthesis of an Antiaromatic Porphyrinoid
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PDF (114 kb)
1199
Naphthalenes by Microwave-Assisted Dehydrogenative Diels–Alder Reaction
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PDF (96 kb)
1200
Tetrathiafulvalene-Based Microporous Metal-Organic Framework
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HTML
PDF (109 kb)
1201
One-Step Access to Luminescent Pentaaryldiazaboroles
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HTML
PDF (108 kb)
1202
From Masked Diazonium Salts to Boronic Esters
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HTML
PDF (95 kb)
1203
Controlled Radical Polymerization by Turning on the Lights
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PDF (102 kb)
1204
Fusing π-Conjugated Heterocycles
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PDF (124 kb)
1205
Mechanical Stress Yields HCl
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PDF (136 kb)
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z1207
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PDF (647 kb)
1207
Asymmetric Conjugate Addition of Phosphines to Ene-Imines
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HTML
PDF (135 kb)
1208
Cu-Catalyzed Asymmetric Cyclopropanation of 1,2-Disubstituted Alkenes
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PDF (105 kb)
1209
Iridium-Catalyzed Enantioconvergent Thioetherification
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PDF (127 kb)
1210
Rhodium-Catalyzed Enantioselective Nucleophilic Allylation of Imines
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PDF (121 kb)
1211
Dehydrogenative Heck Reaction Using Rh(III)
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PDF (109 kb)
1212
Platinum-Catalyzed Hydrative Cycloisomerization
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PDF (99 kb)
1213
Iridium-Catalyzed Asymmetric Hydrogenation of α-Substituted Acrylic Acids
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HTML
PDF (127 kb)
1214
Asymmetric Epoxidation of Conjugated Olefins with Dioxygen
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HTML
PDF (105 kb)
1215
Enantioselective Synthesis of Tertiary α-Hydroxyketones
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PDF (129 kb)
1216
Diastereoselective Cyclohexyl- and Tetrahydropyranyl Syntheses by Nickel Catalysis
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PDF (100 kb)
1217
Asymmetric Pyrrolidine Synthesis by [3+2] Cycloaddition of α-Silylimines
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HTML
PDF (156 kb)
1218
All-Carbon Macrocycles by Catalytic Gosteli–Claisen Rearrangement
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HTML
PDF (101 kb)
1219
Asymmetric Epoxidation with an Iron–Porphyrin-like Complex
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HTML
PDF (112 kb)
1220
Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation of Ketones
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HTML
PDF (101 kb)
1221
Ruthenium NHC-Catalyzed
Z
- and Enantioselective Cross-Metathesis
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HTML
PDF (112 kb)
1222
C–H Activation and
E
-Double Bond Formation by Ruthenium Catalysis
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HTML
PDF (107 kb)
1223
Asymmetric
ipso
-Friedel–Crafts Alkylation for Quaternary Spirocenters
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HTML
PDF (114 kb)
1224
Iridium-Catalyzed Enantioselective Hydrogenation of Sulfones
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HTML
PDF (104 kb)
1225
Oxazaborolidinium Ion Catalyzed Asymmetric Roskamp Reaction
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HTML
PDF (117 kb)
1226
Iridium-Catalyzed Enantioselective Hydrogenation of Isoquinolines
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HTML
PDF (103 kb)
1227
Ir(I)-Catalyzed Asymmetric Hydrogenation of Seven-Membered Cyclic Imines
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HTML
PDF (101 kb)
1228
Synthesis of Chiral 1,1-Diarylethanes by Stereospecific Nickel Catalysis
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PDF (98 kb)
1229
Ruthenium-Catalyzed Asymmetric Hydrogenation of Imines
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PDF (103 kb)
1230
Copper-Catalyzed Asymmetric Claisen Rearrangement of Enolphosphonates
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PDF (116 kb)
1231
Enantioselective Co-Catalysis to Trap Reactive Zwitterionic Intermediates
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PDF (110 kb)
1232
β,β-Disubstituted Nitroalkene Hydrogenation Using Rhodium
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PDF (128 kb)
1233
Palladium-Catalyzed Stereoselective Direct Substitution of Allylic Amines
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PDF (114 kb)
1234
Rhodium(II) Carbenoids for Alkynoate Synthesis
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PDF (101 kb)
1235
N
,
N
′-Dioxide Scandium Catalyzed Enantioselective Friedel–Crafts Reaction
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PDF (110 kb)
1236
Asymmetric Ring-Expansion of Isatins
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PDF (121 kb)
Metal-Mediated Synthesis
z1237
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PDF (328 kb)
1237
Fe-Catalyzed sp
3
–sp
3
Cross–Coupling
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HTML
PDF (125 kb)
1238
Synthesis of 8-Oxabicyclo[3.2.1]octanes by Cationic Cascade Cyclization
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PDF (106 kb)
1239
Cu(I)-Catalyzed Addition of Nucleophilic Silicon to Propargylic Derivatives
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HTML
PDF (112 kb)
1240
Enantioselective Ti(III)-Catalyzed Reductive Cyclization of Ketonitriles
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HTML
PDF (113 kb)
1241
Palldium-Catalyzed Synthesis of Dihydrocycloocta[
b
]indoles from Iodoindoles
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HTML
PDF (104 kb)
1242
Iron-Mediated Hydrofluorination of Unactivated Alkenes
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HTML
PDF (100 kb)
1243
Stereodivergent Synthesis of Tri- and Tetrasubstituted Alkenes
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HTML
PDF (99 kb)
1244
Double Addition of Grignard Reagents to Acyl Cyanhydrins
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HTML
PDF (111 kb)
1245
Fe-Catalyzed Diastereoselective Cross-Coupling of Cyclic Halohydrins
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HTML
PDF (97 kb)
1246
Fluoroform-Derived CuCF
3
for Trifluoromethylation of Arylboronic Acids
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HTML
PDF (101 kb)
1247
Functionalized 2-Aryloxetanes by Oxetane-Directed
ortho
-Lithiation
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HTML
PDF (108 kb)
1248
Copper-Mediated Cyanation of Indoles and 2-Phenylpyridines
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HTML
PDF (98 kb)
1249
Diastereoselective Addition of Arylzinc Reagents to Sugar Aldehydes
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HTML
PDF (99 kb)
1250
Aryl Carbamates and Sulfamates as Reagents in Fe-Catalyzed Couplings
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HTML
PDF (97 kb)
1251
Trifluoromethylation of Propargylic Derivatives Using (Ph
3
P)
3
Cu(CF
3
)
Volltext
HTML
PDF (96 kb)
Organo- and Biocatalysis
z1253
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Volltext
PDF (317 kb)
1253
Asymmetric Vinylogous Conjugate Additions of γ-Substituted Butenolides
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HTML
PDF (128 kb)
1254
Cinchona Alkaloid-Catalyzed Isomerization of Imines
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HTML
PDF (101 kb)
1255
Organocatalytic Asymmetric Synthesis of Prostaglandin PGF
2α
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HTML
PDF (157 kb)
1256
Catalytic Asymmetric Oxyfluorination of Enamides
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HTML
PDF (124 kb)
1257
H-Bond-Directed Trienamine Catalysis
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HTML
PDF (135 kb)
1258
Superbase-Initiated Mannich Reactions of Sulfonylimidates
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HTML
PDF (106 kb)
1259
Primary Amine Catalyzed Enantioselective Friedel–Crafts Alkylation of Enones
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HTML
PDF (123 kb)
1260
NHC-Catalyzed Enantioselective Synthesis of β,γ-Unsaturated α-Fluoroesters
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HTML
PDF (130 kb)
1261
Catalytic Asymmetric Conjugate Addition of Aldehydes to Acrylates
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HTML
PDF (101 kb)
Polymer-Supported Synthesis
z1263
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Volltext
PDF (371 kb)
1263
A
3
-Coupling Reaction with Au@PMO-IL
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HTML
PDF (109 kb)
1264
Asymmetric Amination with a Polymer-Supported Chiral Rhodium Complex
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HTML
PDF (106 kb)
1265
Borylation of N-Adjacent C(sp
3
)–H Bonds with Silica-TRIP/Rh
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HTML
PDF (136 kb)
1266
A SiO
2
-Supported Pd–Amine Catalyst for the Tsuji–Trost Reaction
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HTML
PDF (102 kb)
1267
Monolith-Supported Flow Synthesis of 2-Aminopyrimidines
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HTML
PDF (108 kb)
1268
Au NPs-Catalyzed Oxidation of Hydrosilanes to Silanols
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HTML
PDF (97 kb)
1269
A Clay-Supported Cu(II) Catalyst for the One-Pot Synthesis of Aryl Triazoles
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HTML
PDF (104 kb)
1270
Carbonylative Cyclization of Halobenzoic Acids with PS-NHC–Pd
Volltext
HTML
PDF (107 kb)
1271
A Silica-Supported Trifluoromethyl Ketone with KHSO
5
for Epoxidation
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HTML
PDF (111 kb)
1272
Epoxidation of Olefins with a Peracid Supported on Silica
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HTML
PDF (102 kb)
1273
Annulation of Quinone Monoacetals with Alkenes Using PS-PFBA
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HTML
PDF (110 kb)
1274
Preparation of Aminoimidazopyridines with γ-Fe
2
O
3
@SiO
2
-OSO
3
H
Volltext
HTML
PDF (133 kb)
1275
Chemoselective Hydrogenation of Carbonyls with Ni–Sn/AlOH
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HTML
PDF (101 kb)
Addenda and Errata
1277
Bottom-up Synthesis of Zigzag Carbon Nanotube Belt Precursors
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HTML
PDF (92 kb)
1278
Fe-Catalyzed Oxyamination of Alkenes with
N
-Sulfonyl Oxaziridines
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HTML
PDF (95 kb)
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