Nickel-Catalyzed Regioselective Olefin-Directed Cross-Coupling Reaction

doi:10.1055/s-2008-1042696

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Synfacts 2008(3): 0288-0288
DOI: 10.1055/s-2008-1042696

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

Nickel-Catalyzed Regioselective Olefin-Directed Cross-Coupling Reaction

Contributor(s): Mark Lautens, Valentina Aureggi
R. L. Rogers, J. L. Moore, T. Rovis*
Colorado State University, Fort Collins, USA

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Publikationsdatum:
21. Februar 2008 (online)

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Significance

The development of an efficient catalytic regioselective alkylation of cyclic anhydrides through olefin-directed nickel insertion and subsequent cross-coupling is reported. The corresponding alkylated products are obtained in good yields and regioselectivities.