Regio- and Enantioselective Cobalt-Catalyzed Allylic Amination
Cobalt-Catalyzed Regio- and Enantioselective Allylic Amination.
J. Am. Chem. Soc. 2019;
17 September 2019 (online)
The authors report an enantioselective cobalt-catalyzed allylic amination of racemic allylic carbonates that leads to highly branched products.
A broad range of aliphatic and aromatic amines are used, providing a variety of amines in excellent yields and enantioselectivities.