Indium(III) Isopropoxide as a Hydrogen Transfer Catalyst for Conversion of Benzylic Alcohols into Aldehydes or Ketones via Oppenauer Oxidation

Yohei Ogiwara; Yuji Ono; Norio Sakai

doi:10.1055/s-0035-1562542

Synthesis, Inhaltsverzeichnis

Synthesis 2016; 48(23): 4143-4148
DOI: 10.1055/s-0035-1562542

paper

Indium(III) Isopropoxide as a Hydrogen Transfer Catalyst for Conversion of Benzylic Alcohols into Aldehydes or Ketones via Oppenauer Oxidation

Yohei Ogiwara

Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba 278-8510, Japan eMail: sakachem@rs.noda.tus.ac.jp

,

Yuji Ono

Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba 278-8510, Japan eMail: sakachem@rs.noda.tus.ac.jp

,

Norio Sakai*

Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science (RIKADAI), Noda, Chiba 278-8510, Japan eMail: sakachem@rs.noda.tus.ac.jp

› Institutsangaben

Abstract

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Abstract

Indium(III) isopropoxide [In(Oi-Pr)₃] was applicable as an Oppenauer oxidation catalyst, and the conversion of primary or secondary alcohols into the corresponding aldehydes or ketones was promoted at room temperature using pivalaldehyde as an oxidant.

Key words

indium catalyst - Oppenauer oxidation - primary alcohol - secondary alcohol - aldehyde - ketone - room temperature

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Referenzen

References

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