Subscribe to RSS
Please copy the URL and add it into your RSS Feed Reader.
https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml
Synfacts 2013; 9(4): 0393
DOI: 10.1055/s-0032-1318401
DOI: 10.1055/s-0032-1318401
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
Chiral Cyclopentadiene Ligands for the Asymmetric Allylation of Benzamides
Further Information
Publication History
Publication Date:
15 March 2013 (online)

Significance
A class of chiral Cp ligands with tuneable steric parameters is reported and used in the Rh(III)-catalyzed allylation of N-methoxybenzamides. The obtained yields are good and the enantioselectivities excellent.
MissingLinkText
Comment
Cyclopentadienyl (Cp) ligands are among the most versatile and frequently used ligands to access robust and highly catalytically active transition-metal complexes. However, there are only a few chiral Cp ligands reported so far.
MissingLinkText
MissingLinkText
