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Synfacts 2013; 9(2): 0195
DOI: 10.1055/s-0032-1318067
DOI: 10.1055/s-0032-1318067
Metal-Mediated Synthesis
Synthesis of Diarylethynyl Methanes via a Multicomponent Coupling
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
18. Januar 2013 (online)
Significance
A straightforward synthesis of diarylethynyl methanes via a titanocene-catalyzed multicomponent coupling has been disclosed. This rapid and divergent reaction furnishes the corresponding products in good to almost quantitative yield.
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Comment
The reported reaction shows a high degree of modularity and convergency in the rapid assembly of complex target molecules. Furthermore, the authors could apply the new protocol to the synthesis of a natural product.
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