Borylation of Aryl Halides with Silica-SMAP/Pd

doi:10.1055/s-0031-1289240

Subscribe to RSS

Please copy the URL and add it into your RSS Feed Reader.

https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000131.xml

Share / Bookmark

Facebook Linkedin Weibo

Download PDF

Synfacts 2011(11): 1262-1262
DOI: 10.1055/s-0031-1289240

Polymer-Supported Synthesis

Borylation of Aryl Halides with Silica-SMAP/Pd

Contributor(s): Yasuhiro Uozumi, Takao Osako
S. Kawamorita, H. Ohmiya, T. Iwai, M. Sawamura*
Hokkaido University, Sapporo, Japan

Further Information

Publication History

Publication Date:
19 October 2011 (online)

Permissions and Reprints

Significance

A silica-supported compact phosphine palladium complex (silica-SMAP/Pd) catalyzed the borylation of sterically demanding aryl halides with bis(pinacolato)diboron to give the corresponding borylation products in up to 99% yield (19 examples).