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Synfacts 2011(7): 0727-0727
DOI: 10.1055/s-0030-1260613
DOI: 10.1055/s-0030-1260613
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag
Stuttgart ˙ New YorkNitrone-Mediated Dendrimer Synthesis
E. H. H. Wong, O. Altintas, M. H. Stenzel, C. Barner-Kowollik*, T. Junkers*
Karlsruhe Institute of Technology, Germany; The University of New South Wales, Sydney, Australia; Universiteit Hasselt, Diepenbeek, Belgium
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Publikationsverlauf
Publikationsdatum:
17. Juni 2011 (online)
Significance
The authors report a new dendrimer synthetic approach based on alternating nitrone-mediated radical coupling (NMRC) and copper-catalyzed azide-alkyne cycloaddition (CuAAC) reactions. Each nitrone group reacts with two radicals and the resulting alkoxyamine bearing two new functional groups serves as branching point.