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Synfacts 2011(7): 0767-0767
DOI: 10.1055/s-0030-1260507
DOI: 10.1055/s-0030-1260507
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New YorkNi-Catalyzed Multicomponent Reaction of Vinylcyclopropane, Alkyne, and Me2Zn
T. Mori, T. Nakamura, M. Kimura*
Nagasaki University, Japan
Further Information
Publication History
Publication Date:
17 June 2011 (online)
Significance
A new nickel-catalyzed regio- and stereocontrolled three-component coupling reaction of alkynes, Me2Zn, and vinyloxacyclopropanes or vinylcyclopropanes to yield dienyl homoallylalcohols and α-dienyl malonates is described.